Controlled variations of quantum phases observed by NMR

通过 NMR 观察到的量子相的受控变化

• 批准号: 1709304
• 负责人: Stuart Brown
• 金额: $ 48.35万
• 依托单位: University of California-Los Angeles
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2017
• 资助国家: 美国
• 起止时间: 2017-08-01 至 2021-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1709304&HistoricalAwards=false
• 关键词: Controlled; variations; quantum; phases; observed

Non-technical abstractA wide range of phenomena of current interest in condensed matter physics are observed in electronic materials where interactions must be taken into account for a proper description. How those correlations are manifest depends on multiple parameters, which can be used to tune the complex systems. For example, the state of matter observed in very low temperatures can be controlled by an external parameter, like magnetic field, strain or carrier doping. Such tuning is performed to investigate new and uncharacterized states of matter, to control the physical properties within one state or another, to provide insight where prevailing understandings break down, and to investigate the potential for applications through optimization. In this project, nuclear magnetic resonance (NMR) is applied in versatile ways to selected systems subjected to variable magnetic fields and uniaxial strain. The specific objectives range from studies of the properties of otherwise inaccessible states of matter, to clarifying questions unresolved by other means. NMR is used because it provides a window into the local electronic environment. Both graduate and undergraduate students are trained in cryogenic, radiofrequency, and simulation technologies, with opportunities to train and collaborate with research groups located at user facilities in the United States and abroad, such as the National MagLab in Tallahassee. In addition to the transfer of science, technology and hardware between research groups initiated by these collaborations, the students benefit from exposure to complementary expertise by way of interactions with scientists working in other areas, and through extended visits to facilities. Technical abstractThis project employs solid state magnetic resonance techniques to address questions associated with quasi-two dimensional superconductors and frustrated quantum magnets. The approach integrates nuclear magnetic resonance (NMR) with different combinations of extreme conditions, specifically uniaxial strain, high magnetic fields, and temperatures ranging to less than 1 K. The objective is to study the nature of induced phases and excitations. NMR is well-suited for this task since the technique is generally sensitive to the local magnetic and charge environment through the hyperfine interaction and nuclear quadrupolar coupling to the electric field gradient. The strain method has potential for broader application since it can be varied continuously in situ; here it will be employed in a compound long-considered a chiral p-wave superconductor. Through transport and susceptibility studies, dramatic, non-monotonic changes in the critical temperature were demonstrated. NMR experiments will inform as to strain-induced changes to both normal and superconducting states, including changes to Fermi surface topology and density of states, identification of an anticipated split superconducting transition, or a transition between different superconducting orders. High magnetic fields will be utilized to stabilize and study the physical properties of inhomogeneous superconductivity in a quasi-2D compound for which where orbital suppression of the superconducting state is avoided as a result of uncommonly large electronic structure anisotropy.

在电子材料中观察到凝聚态物理学中当前感兴趣的广泛现象，其中必须考虑相互作用以进行适当的描述。这些相关性如何表现取决于多个参数，这些参数可用于调整复杂系统。例如，在非常低的温度下观察到的物质状态可以通过外部参数来控制，如磁场，应变或载流子掺杂。进行这种调整是为了研究新的和未表征的物质状态，以控制一种状态或另一种状态内的物理性质，提供洞察力，其中流行的理解打破，并通过优化研究应用的潜力。在这个项目中，核磁共振（NMR）被应用在多功能的方式选择系统受到可变的磁场和单轴应变。具体的目标范围从研究否则无法获得的物质状态的属性，以澄清通过其他手段未解决的问题。使用NMR是因为它提供了一个进入局部电子环境的窗口。研究生和本科生都接受过低温，射频和模拟技术的培训，有机会与位于美国和国外用户设施的研究小组进行培训和合作，例如塔拉哈西的国家MagLab。除了通过这些合作发起的研究小组之间的科学，技术和硬件的转让，学生受益于接触互补的专业知识，通过与在其他领域工作的科学家的互动，并通过延长访问设施。技术摘要本计画利用固态磁共振技术来探讨准二维超导体与受抑量子磁铁的相关问题。该方法将核磁共振（NMR）与极端条件的不同组合相结合，特别是单轴应变，高磁场和温度范围小于1 K。目的是研究感应相位和激励的性质。NMR非常适合于这项任务，因为该技术通常通过超精细相互作用和核四极耦合到电场梯度对局部磁和电荷环境敏感。应变方法具有更广泛的应用潜力，因为它可以在原位连续变化;在这里，它将被用于长期被认为是手性p波超导体的化合物。通过运输和敏感性的研究，戏剧性的，非单调的变化，在临界温度被证明。核磁共振实验将告知应变引起的正常和超导状态的变化，包括费米表面拓扑结构和状态密度的变化，预期分裂超导转变的识别，或不同超导阶之间的转变。高磁场将被用来稳定和研究准二维化合物中的非均匀超导性的物理性质，其中超导态的轨道抑制是由于不常见的大电子结构各向异性而避免的。

项目成果

Dipolar order in an amphidynamic crystalline metal–organic framework through reorienting linkers

• DOI: 10.1038/s41557-020-00618-6
• 发表时间: 2021-02
• 期刊: Nature Chemistry
• 影响因子: 21.8
• 作者: Y.-S. Su;E. Lamb;I. Liepuoniute;A. Chronister;A. L. Stanton;P. Guzman;S. Pérez-Estrada;T. Chang;K. Houk;M. Garcia‐Garibay;S. Brown

Critical temperature Tc and Pauli limited critical field of Sr2RuO4 : Uniaxial strain dependence

Sr2RuO4 的临界温度 Tc 和泡利极限临界场：单轴应变依赖性

• DOI: 10.1103/physrevb.102.014509
• 发表时间: 2020
• 期刊: Physical Review B
• 影响因子: 3.7
• 作者: Yu, Yue;Brown, Stuart;Raghu, S.;Yang, Kun
• 通讯作者: Yang, Kun

Constraints on the superconducting order parameter in Sr2RuO4 from oxygen-17 nuclear magnetic resonance

• DOI: 10.1038/s41586-019-1596-2
• 发表时间: 2019-10-03
• 期刊: NATURE
• 影响因子: 64.8
• 作者: Pustogow, A.;Luo, Yongkang;Brown, S. E.
• 通讯作者: Brown, S. E.

Impurity moments conceal low-energy relaxation of quantum spin liquids

• DOI: 10.1103/physrevb.101.140401
• 发表时间: 2019-11
• 期刊: Physical Review B
• 影响因子: 3.7
• 作者: A. Pustogow;T. Le;H.-H. Wang-H.;Yongkang Luo;E. Gati;H. Schubert;M. Lang;S. Brown