MRI: Acquisition of a Thermal Ionization Mass Spectrometer for High-Precision Geochronology and Isotope Geology

MRI：购买热电离质谱仪进行高精度地质年代学和同位素地质学

• 批准号: 1726099
• 负责人: Blair Schoene
• 金额: $ 52.25万
• 依托单位: Princeton University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2017
• 资助国家: 美国
• 起止时间: 2017-09-01 至 2020-02-29
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1726099&HistoricalAwards=false
• 关键词: MRI; Acquisition; Thermal; Ionization; Mass

Determining the rates of geologic processes over thousand to billion year time scales requires the determination of isotopic ratios with very high precision on a wide range of Earth materials. Precise and accurate measurements of radioactive and radiogenic isotopes provides the basis for geochronology, which in addition to other types of isotopic data, can be used to unravel ties between causation versus coincidence in events such as mass extinctions, climate change, the pace of biotic evolution, and provide a more detailed understanding of the physics of mass and heat transfer that drive plate tectonics and volcanic eruptions. This MRI grant provides funds to purchase a thermal ionization mass spectrometer (TIMS) in the Department of Geosciences at Princeton University, which focuses on measuring high-precision isotope ratios that are essential for determining the age of Earth materials and understanding the rates of geologic processes. This new instrument will supplement an existing TIMS managed by PI Schoene. The enhanced capacity provided by the new TIMS will permit the lab to broaden its research focus and secure ties between the research programs of Schoene and co-PI Higgins, as well as other faculty in the department and within a broad geoscience community. The new TIMS will serve to 1) increase the capacity of a world-class U-Pb lab to host and train internal and external users from a broad spectrum of universities, including liberal arts colleges, 2) devote more time to exploring and exploiting new isotopic systems, 3) further increase the precision and accuracy of these techniques to benefit the geochronologic and isotope geology communities, 4) expand the devotion of Schoene and Higgins towards integrating research and class work, and 5) build on existing programs led by Higgins to engage and educate local urban communities in the dangers of, and science behind, environmental and anthropogenic Pb contamination. This MRI grant provides funds to purchase a new TIMS in the Department of Geosciences at Princeton University to be managed by PI Schoene and co-PI Higgins, which will supplement an existing TIMS currently managed by Schoene. The new instrument will be housed in an existing space adjacent to state-of-the-art geochemistry facilities, be supported by existing clean labs for sample preparation, and also supplement the research capabilities of existing ICPMS facilities led by Higgins. The existing TIMS and ICPMS facilities have developed a track record of serving the demand for geochronologic and isotopic data within a broad geoscience community; they also devote substantial time to establishing techniques and workflows that both ensure the precision and accuracy of routine methods and enable new science. The focus of the current TIMS is on the numerous applications of U-Pb geochronology; the new instrument will expand those capabilities and also devote time to measuring stable and radiogenic Sr and Ca isotopes. The new instrument will also permit the PIs to host more external users, thus broadening the impact of the laboratories and providing much-needed high-precision geochronologic and isotopic data to a wide-range of users from Universities that may not have the infrastructure to host similar laboratories. Targeted Geoscience research projects range from understanding the evolution of continents and volcanic systems, calibrating rates of climate change in the deep past through geochronology of stratigraphic sections, extending the reach of ice-core records for tracking atmospheric composition beyond a million years ago, measuring the flux of flood basalt eruptions and understanding their environmental impact, and increasing the precision and accuracy of geochronology of Lunar samples.

要确定数千年至数十亿年时间尺度上的地质作用速率，需要在广泛的地球物质上以非常高的精度确定同位素比率。放射性和放射性同位素的精确和准确测量为地质年代学提供了基础，除了其他类型的同位素数据外，可以用来解开诸如质量迁移，气候变化，生物进化速度等事件中因果关系与巧合之间的联系，并提供更详细的了解驱动板块构造和火山爆发的质量和热量转移的物理学。该MRI赠款提供资金，用于购买普林斯顿大学地球科学系的热电离质谱仪（TIMS），该质谱仪专注于测量高精度同位素比率，这对于确定地球物质的年龄和了解地质过程的速率至关重要。这一新仪器将补充PI Schoene管理的现有TIMS。新的TIMS提供的增强能力将使实验室能够扩大其研究重点，并确保Schoene和co-PI Higgins以及该部门和广泛的地球科学社区内的其他教师的研究计划之间的联系。 新的TIMS将有助于1）提高世界级U-Pb实验室的能力，以接待和培训来自广泛大学（包括文科学院）的内部和外部用户，2）投入更多时间探索和开发新的同位素系统，3）进一步提高这些技术的精度和准确性，以造福地质年代学和同位素地质学界，4）扩大舍恩和希金斯对整合研究和课堂工作的投入，以及5）建立在希金斯领导的现有计划的基础上，参与和教育当地城市社区的危险，以及环境和人为铅污染背后的科学。这项MRI赠款提供资金，用于在普林斯顿大学地球科学系购买一个新的TIMS，由PI Schoene和共同PI Higgins管理，这将补充目前由Schoene管理的现有TIMS。新仪器将被安置在与最先进的地球化学设施相邻的现有空间中，由现有的清洁实验室支持样品制备，并补充希金斯领导的现有ICPMS设施的研究能力。 现有的TIMS和ICPMS设施已经开发了一个跟踪记录，服务于广泛的地球科学界对地质年代学和同位素数据的需求;他们还投入了大量的时间来建立技术和工作流程，既确保常规方法的精度和准确性，又使新的科学成为可能。目前TIMS的重点是U-Pb地质年代学的众多应用;新仪器将扩大这些能力，并将时间用于测量稳定的和放射成因的Sr和Ca同位素。新的仪器还将使研究所能够接待更多的外部用户，从而扩大实验室的影响，并向可能没有基础设施接待类似实验室的大学的广泛用户提供急需的高精度地质年代学和同位素数据。有针对性的地球科学研究项目包括了解大陆和火山系统的演变，通过地层剖面的地质年代学校准过去深部的气候变化率，将冰芯记录的范围扩大到一百万年前，以跟踪大气成分，测量洪水玄武岩喷发的通量并了解其环境影响，提高月球样品年代学的精度和准确性。

项目成果

U–Pb ID-TIMS geochronology using ATONA amplifiers

• DOI: 10.1039/d0ja00135j
• 发表时间: 2020-06
• 期刊: Journal of Analytical Atomic Spectrometry
• 影响因子: 3.4
• 作者: D. Szymanowski;B. Schoene