Electrochemical Separation and Recovery of Metals from Liquid Alloys

液态合金中金属的电化学分离和回收

• 批准号: 1760025
• 负责人: Antoine Allanore
• 金额: $ 35.74万
• 依托单位: Massachusetts Institute of Technology
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-09-15 至 2022-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1760025&HistoricalAwards=false
• 关键词: Electrochemical; Separation; Recovery; Metals; Liquid

The research made possible by this award will explore faster, safer, and more sustainable methods of precious metal recycling. This will guide researchers toward understanding the science behind the processing of materials. By virtue of its higher productivity, this new method can be utilized to the benefit of the US manufacturing economy. Precious metals have seen an increased prevalence in electronics; unfortunately, these devices have short lifetimes as they are quickly discarded for newer models. This grant supports investigation of a new method for metal recycling, called electrometallurgy, which makes use of electric fields to separate and recycle metals from scrap. This approach provides substantial benefits over existing methods for metal separation, which involve combustion or harsh acid dissolution. This fundamental research will investigate how electricity can be used to selectively recycle and purify the many different metals contained in electronic waste, targeting the precious metals (gold and silver). Bringing together the fields of processing science, thermodynamics, chemical engineering, and electrochemistry, this cross-disciplinary work will bring new knowledge of benefit to engineers in multiple fields. The basic principles developed can be extended to the sustainable production of metals for aerospace and defense, construction, and technology, presenting a large benefit to the US economy as well as public health. Furthermore, the computational tools developed in this work will be made widely available as free teaching tools for thermodynamics. This online tool will reach a broad and diverse audience, empowering students to pursue science and engineering. When compared to other recycling methods, electrometallurgy has the potential to reduce the energy use by 80x and the time needed for recycling by a factor of 10. In order to realize these benefits, however, the electrochemistry of liquid alloy electrodes must be better understood in order to be able to control which metal, among the many present in electronic waste (e-waste), is recycled. Furthermore, a high-temperature solvent, the first of its kind able to accommodate molten gold, copper, and silver simultaneously, will be investigated. This research aims to understand the underlying kinetic, transport, and thermodynamic factors that determine which species is reduced at the cathode and oxidized at the anode made of melted e-waste. A new model predicting which metals are stable and in what proportions will be developed. In addition, the rate-limiting step in the process will be verified with experimental electrochemical measurements. Advanced electrochemical characterization techniques, such as alternating current cyclic voltammetry, alongside traditional chronoamperometry and electromotive force measurements, will be employed experimentally. Mutiphysics modeling, thermodynamic calculations, and phase diagram predictions will be used to iterate and optimize process conditions on the computational side. Together, both experimental and modeling techniques will inform the underlying fundamentals of electrochemical behavior of molten precious metals.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

该奖项的研究将探索更快，更安全，更可持续的贵金属回收方法。这将指导研究人员了解材料加工背后的科学。由于其更高的生产率，这种新方法可以用于美国制造业经济的利益。贵金属在电子产品中的普及率越来越高;不幸的是，这些设备的寿命很短，因为它们很快就被丢弃用于新型号。这项拨款支持研究一种新的金属回收方法，称为电冶金，它利用电场从废料中分离和回收金属。这种方法提供了优于现有的金属分离方法的实质性益处，现有的金属分离方法涉及燃烧或强酸溶解。这项基础研究将研究如何利用电力来选择性地回收和净化电子废物中含有的许多不同金属，目标是贵金属（金和银）。汇集了加工科学，热力学，化学工程和电化学领域，这种跨学科的工作将为多个领域的工程师带来有益的新知识。开发的基本原则可以扩展到航空航天和国防，建筑和技术金属的可持续生产，为美国经济和公众健康带来巨大利益。此外，在这项工作中开发的计算工具将作为热力学的免费教学工具广泛使用。这个在线工具将覆盖广泛而多样化的受众，使学生能够追求科学和工程。与其他回收方法相比，电冶金有可能将能源使用减少80倍，回收所需时间减少10倍。然而，为了实现这些好处，必须更好地理解液态合金电极的电化学，以便能够控制电子废物中存在的许多金属中的哪一种金属被回收。此外，高温溶剂，其第一种能够容纳熔融的金，铜，和银同时，将进行研究。这项研究旨在了解潜在的动力学，运输和热力学因素，这些因素决定了哪些物种在阴极被还原，哪些物种在由熔化的电子废物制成的阳极被氧化。一个新的模型预测哪些金属是稳定的，以及将开发的比例。此外，该过程中的限速步骤将通过实验电化学测量进行验证。先进的电化学表征技术，例如交流循环伏安法，以及传统的计时电流法和电动势测量，将在实验中使用。多物理模型、热力学计算和相图预测将用于在计算方面优化和优化工艺条件。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Non-standard state thermodynamics of metal electrodeposition

金属电沉积非标态热力学

• 发表时间: 2021
• 期刊: Electrochimica acta
• 影响因子: 6.6
• 作者: Wagner, Mary-Elizabeth;Allanore, Antoine
• 通讯作者: Allanore, Antoine

Electrochemical Separation of Ag2S and Cu2S from Molten Sulfide Electrolyte

从熔融硫化物电解质中电化学分离 Ag2S 和 Cu2S

• 发表时间: 2022
• 期刊: Journal of the Electrochemical Society
• 影响因子: 3.9
• 作者: Wagner, Mary-Elizabeth;Allanore, Antoine
• 通讯作者: Allanore, Antoine