Investigation of energy density limitation for lithium sulfur batteries

锂硫电池能量密度限制研究

• 批准号: 1805288
• 负责人: Jim Zheng
• 金额: $ 40万
• 依托单位: Florida State University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-09-01 至 2021-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1805288&HistoricalAwards=false
• 关键词: Investigation; energy; density; limitation; lithium

Lithium ion batteries have limited energy density, and an alternative battery chemistry is needed to continue to transform the current energy landscape. Rechargeable lithium-sulfur (Li-S) batteries are among the most promising high-energy-density electrochemical devices for future energy storage applications. However, there are intrinsic limitations that potentially lower the achievable energy density of Li-S batteries. To date, performance of this battery type has been limited by capacity loss and degradation due to permanent loss of active material (sulfur) from the electrode and from reactions of the electrode with the electrolyte. To date, developers have used excess electrolyte to dilute the side reactions that occur that result in lowered performance. This project will use combined experimental and theoretical approaches to study critical issues for high-loading and high-energy Li-S batteries. Specially designed cathode structures and electrolyte configurations will be built to analyze the effects of Li polysulfide species (LiPS) solubility on cell capacity and battery specific energy. The project will yield knowledge on the operating conditions that lead to capacity loss and degradation. The project will also integrate the research outcomes into publicly available electrochemical system simulator (ESS). The fundamental research project will focus on using combined experimental and theoretical approaches to study two critical issues for high loading and high energy Li-S batteries. The first theme includes studies of the effect of lithium polysulfide (LiPS) solubility on cell capacity. Experiments will address the creation of LiPS saturated conditions with different and well-defined initial states-of-discharge and then the characterization of Li-S cell performance under these LiPS saturated conditions. The experiments will also investigate the rate dependence of the potential reaction pathways for LiPS reduction. The second theme addresses experimental verification and theoretical modeling of solid product deposition on the cathode. Focus of this theme is on the study of the Li2S/Li2S2 deposition process using electrochemical measurement combined with material characterization methods, including transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The accompanying feasibility modeling of a Li-S battery will incorporate the experimental verified solid product deposition process, as well as the analysis of the LiPS solubility effect in the built model. The fundamental knowledge and outcomes of this project will also be incorporated into an Electrochemical Systems Simulator (ESS) which is a simulation package for electrochemical systems that incorporates the theoretical models into a user-friendly battery and circuit simulator. The ESS will be a unified framework, in which users can define their own electrochemical devices, discretize them on finite element grids, and perform one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) simulations to study the transport and predict charge and discharge curves and the electrochemical impedance spectra of the cells.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

锂离子电池的能量密度有限，需要一种替代电池化学来继续改变当前的能源格局。可再充电锂硫（Li-S）电池是未来能量存储应用中最有前途的高能量密度电化学装置之一。然而，存在潜在地降低Li-S电池可实现的能量密度的固有限制。迄今为止，这种电池类型的性能受到容量损失和退化的限制，这是由于活性材料（硫）从电极和从电极与电解质的反应的永久损失。迄今为止，开发人员已经使用过量的电解质来稀释导致性能下降的副反应。该项目将使用实验和理论相结合的方法来研究高负载和高能量Li-S电池的关键问题。特别设计的阴极结构和电解质配置将被构建，以分析锂多硫化物物种（LiPS）的溶解度对电池容量和电池比能量的影响。该项目将产生关于导致能力损失和退化的操作条件的知识。该项目还将把研究成果整合到公开的电化学系统模拟器（ESS）中。 该基础研究项目将侧重于使用实验和理论相结合的方法来研究高负载和高能量锂硫电池的两个关键问题。第一个主题包括研究多硫化锂（LiPS）溶解度对电池容量的影响。实验将解决具有不同且明确定义的初始放电状态的LiPS饱和条件的创建，然后在这些LiPS饱和条件下表征Li-S电池性能。实验还将研究LiPS还原的潜在反应途径的速率依赖性。第二个主题是固体产物在阴极上沉积的实验验证和理论建模。本主题的重点是使用电化学测量结合材料表征方法，包括透射电子显微镜（TEM）和X射线光电子能谱（XPS），对Li 2S/Li 2S 2沉积过程进行研究。Li-S电池的附带可行性建模将结合实验验证的固体产物沉积过程，以及对所建模型中LiPS溶解度效应的分析。该项目的基本知识和成果也将被纳入电化学系统模拟器（ESS），这是一个电化学系统的模拟包，将理论模型纳入用户友好的电池和电路模拟器。ESS将是一个统一的框架，用户可以在其中定义自己的电化学设备，在有限元网格上离散它们，并执行一维（1D），二维（2D），三维（3D）该奖项反映了NSF的法定使命，被认为是值得的，通过使用基金会的知识价值和更广泛的影响审查标准进行评估来提供支持。

项目成果

A simple and scalable pre-lithiation approach for high energy and low cost lithium ion sulfur batteries

一种用于高能量和低成本锂离子硫电池的简单且可扩展的预锂化方法

• 发表时间: 2020
• 期刊: Journal of the Electrochemical Society
• 影响因子: 3.9
• 作者: Chao Shen, Donghao Ye

Communication—A Simple and Scalable Pre-Lithiation Approach for High Energy and Low Cost Lithium Ion Sulfur Batteries

• DOI: 10.1149/1945-7111/ab8408
• 发表时间: 2020-04
• 期刊: Journal of The Electrochemical Society
• 影响因子: 3.9
• 作者: Chao Shen;D. Ye;Liming Jin;P. Andrei;Jim P. Zheng

Self-Discharge Behavior of Lithium-Sulfur Batteries at Different Electrolyte/Sulfur Ratios

• DOI: 10.1149/2.0461903jes
• 发表时间: 2019-01-02
• 期刊: JOURNAL OF THE ELECTROCHEMICAL SOCIETY
• 影响因子: 3.9
• 作者: Shen, Chao;Xie, Jianxin;Zheng, Jim P.
• 通讯作者: Zheng, Jim P.

Stable cycling of lithium-sulfur batteries by optimizing the cycle condition

• DOI: 10.1016/j.electacta.2019.134948
• 发表时间: 2019-12
• 期刊: Electrochimica Acta
• 影响因子: 6.6
• 作者: Chao Shen;P. Andrei;Jim P. Zheng

A Li-Li2S4 battery with improved discharge capacity and cycle life at low electrolyte/sulfur ratios

• DOI: 10.1016/j.jpowsour.2019.01.029
• 发表时间: 2019-02
• 期刊: Journal of Power Sources
• 影响因子: 9.2
• 作者: Chao Shen;Jianxin Xie;Mei Zhang;P. Andrei;Jim P. Zheng;M. Hendrickson;E. Plichta