Ultracold Molecular Ions Prepared Via Sympathetic Cooling - A New Frontier for Quantum Interactions and Fundamental Physics

通过交感冷却制备超冷分子离子——量子相互作用和基础物理学的新领域

• 批准号: 1806288
• 负责人: Eric Hudson
• 金额: $ 52万
• 依托单位: University of California-Los Angeles
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-09-01 至 2021-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1806288&HistoricalAwards=false
• 关键词: Ultracold; Molecular; Ions; Prepared; Via

This award supports the development of techniques to open and explore a new frontier in physics: the production and study of ultracold polar molecular ions. It is expected that the ability to produce such samples could lead to significant technological and fundamental scientific advancements. This includes potentially learning how to control chemistry in the quantum regime, which could aid novel materials and drug design; creating a platform that could be useful in producing a robust and scalable quantum computer; allowing new probes of quantum matter and charge transport; understanding the formation of interstellar clouds; and precision measurement of molecular structure for tests of fundamental physics. The main research objective of this project is to further optimize the methods of cold polar molecular ion production and begin developing the techniques necessary to enable the expected technological and fundamental advancements. As such, this project has the ability to aid the progress of science and in the longer term bolster national prosperity and security.Because molecular ions are easily trapped for many minutes in radio-frequency ion traps, there are possibilities for cooling and interrogation that are not applicable to neutral atoms and molecules. Therefore, this team is developing a technique where molecular ions are co-trapped with laser cooled atomic ions for sympathetic cooling of their motion. The molecules are then immersed in a cloud of laser-cooled calcium atoms which cool the molecular internal quantum states. In this way, cold ground-state molecular ions should be produced. This team will work to answer three challenges facing the field: 1.) Can chemical reactions between atoms and molecular ions be controlled? 2.) Can we produce molecular ions in the absolute internal ground state? 3.) What is the coherence time of the rotational qubit of a molecular ion in a Paul trap?This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

该奖项支持技术开发，以打开和探索物理学的新前沿：超冷极性分子离子的生产和研究。预计生产此类样品的能力将导致重大的技术和基础科学进步。这包括潜在地学习如何控制量子体系中的化学，这可能有助于新材料和药物设计;创建一个平台，可以用于生产一个强大的和可扩展的量子计算机;允许量子物质和电荷传输的新探测器;了解星际云的形成;和分子结构的精确测量基础物理测试。该项目的主要研究目标是进一步优化冷极性分子离子的生产方法，并开始开发必要的技术，以实现预期的技术和基本进步。因此，该项目有能力帮助科学进步，并在长期内促进国家繁荣和安全。由于分子离子很容易在射频离子阱中被捕获数分钟，因此有可能进行中性原子和分子不适用的冷却和询问。因此，该团队正在开发一种技术，其中分子离子与激光冷却的原子离子共同捕获，以对其运动进行交感冷却。然后将分子浸入激光冷却的钙原子云中，从而冷却分子的内部量子态。这样，就可以产生冷基态分子离子。该团队将努力应对该领域面临的三个挑战：1。原子和分子离子之间的化学反应能被控制吗？2.）的情况。我们能在绝对内部基态产生分子离子吗？3.）第三章保罗阱中分子离子转动量子比特的相干时间是多少？该奖项反映了NSF的法定使命，并被认为是值得通过使用基金会的知识价值和更广泛的影响审查标准进行评估的支持。

项目成果

Dipolar quantum logic for freely rotating trapped molecular ions

• DOI: 10.1103/physreva.98.040302
• 发表时间: 2018-10-25
• 期刊: PHYSICAL REVIEW A
• 影响因子: 2.9
• 作者: Hudson, Eric R.;Campbell, Wesley C.
• 通讯作者: Campbell, Wesley C.

Excitation-assisted nonadiabatic charge-transfer reaction in a mixed atom-ion system

• DOI: 10.1103/physreva.99.062706
• 发表时间: 2019-06-14
• 期刊: PHYSICAL REVIEW A
• 影响因子: 2.9
• 作者: Li, Ming;Mills, Michael;Kotochigova, Svetlana
• 通讯作者: Kotochigova, Svetlana

Reaction blockading in a reaction between an excited atom and a charged molecule at low collision energy

• DOI: 10.1038/s41557-019-0264-3
• 发表时间: 2019-05
• 期刊: Nature Chemistry
• 影响因子: 21.8
• 作者: P. Puri;Michael Mills;I. Simbotin;J. Montgomery;R. Côté;Christian Schneider;A. Suits;E. Hudson

Dipole-Phonon Quantum Logic with Trapped Polar Molecular Ions

• DOI: 10.1103/physrevlett.125.120501
• 发表时间: 2020-09-14
• 期刊: PHYSICAL REVIEW LETTERS
• 影响因子: 8.6
• 作者: Campbell, Wesley C.;Hudson, Eric R.
• 通讯作者: Hudson, Eric R.

High-resolution collision energy control through ion position modulation in atom-ion hybrid systems

通过原子-离子混合系统中的离子位置调制进行高分辨率碰撞能量控制

• DOI: 10.1063/1.5031145
• 发表时间: 2018
• 期刊: Review of Scientific Instruments
• 影响因子: 1.6
• 作者: Puri, Prateek;Mills, Michael;West, Elizabeth P.;Schneider, Christian;Hudson, Eric R.
• 通讯作者: Hudson, Eric R.