Collaborative Research: InGaN/III-V hybrid integration for high-temperature solar cells

合作研究：用于高温太阳能电池的InGaN/III-V混合集成

• 批准号: 1810265
• 负责人: Minjoo Lee
• 金额: $ 22.5万
• 依托单位: University of Illinois at Urbana-Champaign
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-09-01 至 2022-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1810265&HistoricalAwards=false
• 关键词: Collaborative; Research; InGaN; III; hybrid

Non-technical:Solar cells are increasingly common in many parts of the world, both on rooftops and in large scale solar power stations. Solar cells provide cost-effective power without wires and so are useful for "off-grid" applications. For example, solar cells power sensor networks and provide portable power. They are also the primary power source for satellites, as well as space vehicles used for planetary exploration. Traditional solar cells lose efficiency as temperature increases. Consequently, any place where temperatures exceed 300 degrees Fahrenheit has traditionally been considered off-limits. As a result, innovative power generation schemes that could benefit from the ability to use both heat energy and solar energy at the same time have never been realized. In comparison to Mars, which has been extensively explored by solar-powered robotic vehicles, we know surprisingly little about our very hot nearby neighbors of Venus and Mercury. Solar-powered vehicles could change this. This project aims to advance the burgeoning field of high-temperature solar cells by demonstrating durable new designs that can achieve high efficiency at temperatures above 800 degrees Fahrenheit. Solar cells based on nitrides of Group III elements such as gallium and indium have shown an unusual increase in efficiency with rising temperature. This opens up the possibility of efficient solar cells that operate at high temperature. Beyond the applications above, this project could also lead to sensors that operate efficiently and wirelessly in demanding environments, such as engines. The two co-PIs will seek to incorporate solar cell testing into teacher training programs at their respective institutions. They will also incorporate research into graduate and undergraduate classes and continue their commitment to recruiting under-represented students into STEM careers.Technical:Lee and Zhao aim to combine the unique strengths of III-V and III-N materials using wafer bonding to form multi-junction devices optimized for high temperatures of 300-450C. High-temperature solar cells are needed for inner solar system exploration and hybrid photovoltaic-thermal energy systems. III-V solar cells exhibit the highest-known efficiencies, but their performance decreases with increasing temperature. In contrast, III-N solar cells have recently demonstrated the unusual characteristic of increasing in efficiency with rising temperature. The two co-PIs will take an interdisciplinary approach to demonstrate high-efficiency photovoltaics at high temperature, combining epitaxial growth, materials characterization, device fabrication, device testing, and modeling. This project will advance understanding of optoelectronic device performance at high operating temperatures. The impact of thermal energy on phenomena such as thermionic emission and radiative recombination have widely been studied at cryogenic temperatures, with less attention paid to elevated temperatures of 300-450C. The co-PIs hypothesize that optoelectronic devices can be redesigned to account for and, in some cases, take advantage of such elevated temperatures.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术性：太阳能电池在世界上许多地方越来越普遍，无论是在屋顶上，还是在大型太阳能发电站中。太阳能电池在没有电线的情况下提供具有成本效益的电力，因此对“离网”应用非常有用。例如，太阳能电池为传感器网络供电，并提供便携电力。它们也是卫星以及用于行星探测的航天器的主要动力源。随着温度的升高，传统太阳能电池的效率会下降。因此，任何温度超过300华氏度的地方传统上都被认为是禁区。因此，可以从同时利用热能和太阳能的能力中受益的创新发电计划从未实现。与已经被太阳能驱动的机器人飞行器广泛探索的火星相比，我们对附近非常炎热的邻居金星和水星的了解令人惊讶地少之又少。太阳能汽车可能会改变这一点。该项目旨在通过展示耐用的新设计，在800华氏度以上的温度下实现高效率，来推动高温太阳能电池这一新兴领域的发展。基于第三族元素氮化物的太阳能电池，如镓和铟，随着温度的上升显示出不同寻常的效率提高。这为在高温下工作的高效太阳能电池提供了可能性。除了上述应用，该项目还可能导致传感器在苛刻的环境中高效和无线地运行，例如发动机。这两个联合PIS将寻求将太阳能电池测试纳入各自机构的教师培训计划。他们还将把研究纳入研究生和本科课程，并继续致力于招收未被充分代表的学生进入STEM职业生涯。技术：Lee和赵的目标是利用晶片键合将III-V和III-N材料的独特优势结合在一起，形成针对300-450℃高温进行优化的多结器件。高温太阳能电池是太阳系内部探索和光伏热能混合系统所需要的。III-V太阳能电池显示出已知的最高效率，但它们的性能随着温度的升高而下降。相比之下，III-N太阳能电池最近表现出了随着温度上升而提高效率的不同寻常的特征。这两个合作PI将采用跨学科的方法展示高温下的高效光伏，结合外延生长、材料表征、器件制造、器件测试和建模。该项目将促进对光电子器件在高温下的性能的理解。在低温下，热能对热离子发射和辐射复合等现象的影响已经得到了广泛的研究，但对300-450℃的高温关注较少。共同PIS假设，光电设备可以重新设计，以应对并在某些情况下利用这种高温。这一奖项反映了NSF的法定使命，并通过使用基金会的智力优势和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Metamorphic front- and rear-junction 1.7 eV GaInP solar cells with high open-circuit voltage

具有高开路电压的变质前后结 1.7 eV GaInP 太阳能电池

• DOI: 10.1016/j.solmat.2023.112435
• 发表时间: 2023
• 期刊: Solar Energy Materials and Solar Cells
• 影响因子: 6.9
• 作者: Kim, Mijung;Sun, Yukun;Hool, Ryan D.;Lee, Minjoo Larry
• 通讯作者: Lee, Minjoo Larry

Metamorphic 1.7 eV InGaP front- and rear-junction solar cells with high open- circuit voltage

具有高开路电压的变质 1.7 eV InGaP 前结和后结太阳能电池

• DOI: 10.1109/pvsc43889.2021.9518897
• 发表时间: 2021
• 期刊: 2021 IEEE 48th Photovoltaic Specialists Conference (PVSC
• 作者: Kim, Mijung;Sun, Yukun;Hool, Ryan D.;Lee, Minjoo Larry
• 通讯作者: Lee, Minjoo Larry

Improving the performance of GaInP solar cells through rapid thermal annealing and delta doping

• DOI: 10.1016/j.solmat.2022.111725
• 发表时间: 2022-07
• 期刊: Solar Energy Materials and Solar Cells
• 影响因子: 6.9
• 作者: Yukun Sun;Brian D. Li;R. Hool;S. Fan;Mijung Kim;M. Lee

Current-Matched III–V/Si Epitaxial Tandem Solar Cells with 25.0% Efficiency

• DOI: 10.1016/j.xcrp.2020.100208
• 发表时间: 2020-09
• 作者: S. Fan;Zhengshan J. Yu;R. Hool;P. Dhingra;W. Weigand;Mijung Kim;E. D. Ratta;Brian D. Li;Yukun Sun;Z. Holman;M. Lee