Collaborative Research: Unmanned Aerial Vehicles for Emissions and Chemistry of Volatile Organic Compounds over the Amazon Tropical Forest

合作研究：无人机对亚马逊热带森林上空挥发性有机化合物的排放和化学分析

• 批准号: 1829025
• 负责人: Scot Martin
• 金额: $ 59.47万
• 依托单位: Harvard University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-09-01 至 2022-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1829025&HistoricalAwards=false
• 关键词: Collaborative; Research; Unmanned; Aerial; Vehicles

This project will improve the understanding of atmospheric chemistry processes over tropical forest ecosystems. A mobile profiling system will be used to characterize emissions and deposition of volatile organic compounds (VOC) over horizontal and vertical scales across different forest sub-types. The data will be collected during a series of drone-enabled experiments conducted in both wet and dry seasons in the Adolfo Ducke Forest Reserve, located on the northern outskirts of Manaus Brazil in central Amazonia. The results will be used to improve atmospheric chemistry modeling and databases that characterize the emissions of biogenic compounds from vegetation.The scientific questions that will be addressed during this project include the following: (1) What is the horizontal heterogeneity in the magnitude and types of VOC emission and deposition for forest landscapes that vary on intermediate scales of 100's m? (2) What is the vertical heterogeneity and diel cycle of reactive VOCs in a turbulent planetary boundary layer? and (3) What is the vertical heterogeneity in the speciation and concentration of semivolatile organic compounds (SVOC) produced as photochemical reaction products of VOC oxidation?The horizontal protocol will characterize the spatial variability of the sampled VOCs at intermediate scale and be used to constrain and improve MEGAN (Model of Emissions of Gases and Aerosols from Nature), a framework used for modeling biogenic emissions. The data obtained by the vertical protocol will be used with the mixed-layer inverse-model technique to estimate VOC fluxes. The data and insights gained from this effort will be used to constrain and improve current chemical transport models of atmospheric oxidation and to provide a better understanding of regional and global chemical transport in Amazonia, especially as related to mechanisms of SVOCs and particulate matter production and susceptibility to future Earth-system changes.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

该项目将提高对热带森林生态系统大气化学过程的认识。 将使用一个移动的剖面分析系统，在水平和垂直尺度上对不同森林亚类的挥发性有机化合物的排放和沉积进行定性。 这些数据将在Adolfo Ducke森林保护区进行的一系列无人机实验中收集，该保护区位于亚马逊河流域中部马瑙斯巴西的北方郊区。 研究结果将用于改进大气化学模型和数据库，以表征植被中生物源化合物的排放。在本项目期间将解决的科学问题包括：（1）在100 m的中间尺度上变化的森林景观中，VOC排放和沉积的大小和类型的水平异质性是什么？ (2)在湍流的行星边界层中活性挥发性有机化合物的垂直不均匀性和昼夜循环是什么？（3）半挥发性有机化合物（SVOC）氧化的光化学反应产物的形态和浓度的垂直不均匀性是什么？水平协议将在中间尺度上表征采样VOCs的空间变异性，并用于约束和改进MEGAN（天然气和气溶胶排放模型），这是一个用于模拟生物排放的框架。 垂直协议获得的数据将与混合层反演模型技术，以估计挥发性有机化合物通量。从这项工作中获得的数据和见解将用于限制和改进目前的大气氧化化学迁移模型，并更好地了解亚马逊地区的区域和全球化学迁移，特别是与SVOCs和颗粒物产生机制以及对未来地球的敏感性有关-该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

River winds and pollutant recirculation near the Manaus city in the central Amazon

• DOI: 10.1038/s43247-021-00277-6
• 发表时间: 2021-10
• 期刊: Communications Earth & Environment
• 影响因子: 7.9
• 作者: Tianning Zhao;Jianhuai Ye;I. Ribeiro;Yongjing Ma;H. Hung;Carla E. Batista;Matthew P. Stewart;Patricia Guimarães;J. Vilà‐Guerau de Arellano;R. D. de Souza;A. Guenther;S. Martin

Intermediate-scale horizontal isoprene concentrations in the near-canopy forest atmosphere and implications for emission heterogeneity

• DOI: 10.1073/pnas.1904154116
• 发表时间: 2019-09-24
• 期刊: PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
• 影响因子: 11.1
• 作者: Batista, Carla E.;Ye, Jianhuai;Martin, Scot T.
• 通讯作者: Martin, Scot T.

Near-canopy horizontal concentration heterogeneity of semivolatile oxygenated organic compounds and implications for 2-methyltetrols primary emissions

• DOI: 10.1039/d0ea00006j
• 发表时间: 2021-01
• 期刊: Environmental Science: Atmospheres
• 作者: Jianhuai Ye;Carla E. Batista;Patricia Guimarães;I. Ribeiro;C. Vidoudez;R. Barbosa;R. Oliveira;Yongjing Ma;K. Jardine;J. Surratt;A. Guenther;Rodrigo A. F. Souza;S. Martin

River Winds and Transport of Forest Volatiles in the Amazonian Riparian Ecoregion

亚马逊河岸生态区的河风和森林挥发物的输送

• DOI: 10.1021/acs.est.1c08460
• 发表时间: 2022
• 期刊: Environmental Science & Technology
• 影响因子: 11.4
• 作者: Ye, Jianhuai;Batista, Carla E.;Zhao, Tianning;Campos, Jesus;Ma, Yongjing;Guimarães, Patricia;Ribeiro, Igor O.;Medeiros, Adan S.;Stewart, Matthew P.;Vilà-Guerau de Arellano, Jordi
• 通讯作者: Vilà-Guerau de Arellano, Jordi

Vertical Profiles of Atmospheric Species Concentrations and Nighttime Boundary Layer Structure in the Dry Season over an Urban Environment in Central Amazon Collected by an Unmanned Aerial Vehicle

• DOI: 10.3390/atmos11121371
• 发表时间: 2020-12
• 期刊: Atmosphere
• 影响因子: 2.9
• 作者: Patricia Guimarães;Jianhuai Ye;Carla E. Batista;R. Barbosa;I. Ribeiro;A. Medeiros;Tianning Zhao