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CAREER: Material-Process-Property Relationships of Additive Manufacturing with Polymer Nanocomposites

职业：聚合物纳米复合材料增材制造的材料-工艺-性能关系

基本信息

批准号：
1846758
负责人：
Bulent Gozen
金额：
$ 50万
依托单位：
Washington State University
依托单位国家：
美国
项目类别：
Standard Grant
财政年份：
2019
资助国家：
美国
起止时间：
2019-04-01 至 2025-03-31
项目状态：
未结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=1846758&HistoricalAwards=false
关键词：
CAREER Material Process Property Relationships

项目摘要

This Faculty Early Career Development (CAREER) Program grant will support research into polymer nanocomposites or PNs, consisting of nanoparticles within a polymer matrix. These systems combine favorable properties of the polymers, e.g. light weight, mechanical toughness and flexibility, and the fillers with their high strength, electrical and thermal conductivity, in a tunable fashion. Such combinations lead to unique overall properties that cannot be achieved by conventional materials. These materials are utilized in many emerging technologies such as energy storage, biochemical sensing, flexible electronics and artificial tissue engineering important to the national prosperity and competitiveness. A primary challenge in realizing PNs involves the development of new manufacturing methods to process these materials with high resolution and precise control over filler morphology within the final product that dictates the final part properties. Emerging additive manufacturing methods, particularly direct-ink-writing (DIW), where the PN "inks" are dispensed through nozzles and deposited with high spatial control, has been shown to achieve high resolution manufacturing of PN parts with controllable filler morphologies. This award supports the fundamental research that will provide the knowledge needed for additively manufacturing PN parts having "as-designed" properties with high customizability, precision and accuracy. This capability will enable many emerging technologies critical to societal health, national security and the energy sector such as customizable biochemical sensors, high performance energy storage devices and lightweight high-strength military equipment manufacturing. The educational effort will provide a model for integration of additive manufacturing into the mechanical engineering curriculum which in turn will equip the next generation manufacturing workforce with a much needed skill-set. The outreach activities that will be realized in this project will increase the public awareness and readiness for the additive manufacturing and flexible electronics concepts.Despite the promising potential of additive manufacturing in processing of PNs, there exists a knowledge gap in regard to relationships between raw material properties-process parameters-final part properties. This research will address this knowledge gap through an experimental and computational modeling framework that will reveal the deposition mechanisms influencing the final part properties. To this end, PN inks will be modeled through a new viscoelastic material model that incorporates the effect of temporally and spatially varying filler morphology on the bulk ink rheology. This model will be used in experimentally validated computational fluid dynamics simulations that will output critical stress and strain parameters in the deposited filaments during the printing process. Finally, studies will be conducted to understand how these model outputs translate to specific morphologies of nanoparticles as well as the electrical and mechanical properties of the manufactured parts.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

这项教师早期职业发展（Career）计划拨款将支持聚合物纳米复合材料或PNs的研究，该材料由聚合物基质中的纳米颗粒组成。这些系统以可调的方式结合了聚合物的有利特性，例如重量轻，机械韧性和柔韧性，以及具有高强度，导电性和导热性的填料。这种组合导致了传统材料无法实现的独特整体性能。这些材料被用于许多新兴技术，如能源存储、生化传感、柔性电子和人工组织工程，对国家的繁荣和竞争力至关重要。实现PNs的主要挑战是开发新的制造方法，以高分辨率和精确控制最终产品中的填充物形态来加工这些材料，从而决定最终部件的性能。新兴的增材制造方法，特别是直接油墨书写（DIW），其中PN“墨水”通过喷嘴分配并具有高空间控制沉积，已被证明可以实现具有可控填料形态的PN零件的高分辨率制造。该奖项支持基础研究，为具有高可定制性、精度和准确性的增材制造PN部件提供所需的知识。这种能力将使许多对社会健康、国家安全和能源部门至关重要的新兴技术成为可能，例如可定制的生化传感器、高性能储能设备和轻质高强度军事装备制造。这项教育工作将为将增材制造整合到机械工程课程中提供一个模式，从而为下一代制造业劳动力提供急需的技能。在这个项目中实现的推广活动将提高公众对增材制造和柔性电子概念的认识和准备。尽管增材制造在PNs加工中具有很大的潜力，但在原材料性能-工艺参数-最终零件性能之间的关系方面存在知识差距。本研究将通过实验和计算建模框架来解决这一知识差距，该框架将揭示影响最终零件性能的沉积机制。为此，PN油墨将通过一种新的粘弹性材料模型进行建模，该模型结合了时间和空间变化的填料形态对散装油墨流变学的影响。该模型将用于经过实验验证的计算流体动力学模拟，该模拟将在打印过程中输出沉积细丝的临界应力和应变参数。最后，将进行研究，以了解这些模型输出如何转化为纳米颗粒的特定形态，以及制造零件的电气和机械性能。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。