CAREER: Synthetic Strategies to Optimize Luminescence and Photoredox Properties of Organometallic Complexes

在这个CAREER项目中，由化学学部化学结构、动力学和机制B项目资助，休斯顿大学化学系的Thomas S. Teets教授正在设计新的合成策略来制备发光和光活性铱配合物。该研究的第一个目标是开发出能够发出蓝光的化合物，并可能在长寿命、高效率的有机发光二极管（LED）彩色显示器中发挥作用。第二个目标是开发在光谱的近红外（NIR）区域发射的化合物。这类化合物可用于生物传感和成像。第三个目标是有机合成中的光催化剂化合物，这对新药的开发具有重要意义。这些研究方向由教育和推广组成部分补充，旨在改善普通化学教学，向K-12学生介绍光化学概念，并吸引公众参与科学学习。蒂茨教授正在创建一个在线的、免费的多媒体普通化学教科书，以造福低收入家庭的学生。他还开发了一个名为“点亮分子”的K-12实验室模块，向年轻学生介绍光与化合物的相互作用。最后，他制作了一个名为“颜色的化学”的系列公开讲座，向艺术爱好者介绍视觉艺术中颜色创造背后的化学原理。在这个项目中，Teets教授研究了一类新的蓝磷光环金属化铱配合物，该配合物由无环二氨基羰基和其他非常规羰基配体支撑。这些碳基团破坏了干扰配体场态的稳定性，从而提高了这些蓝色发光化合物的量子产率和稳定性。在光谱的另一端，制备了由富电子、供pi的辅助配体支持的发射nir的双环金属化铱配合物。富电子辅助配体破坏了以铱为中心的最高已占据分子轨道（HOMO）的稳定性，增加了激发态金属到配体的电荷转移（MLCT）特性，增加了辐射速率，提高了光致发光量子产率。采用类似的设计元素，开发了强效可见光光还原剂。这些环金属化铱化合物具有非常还原的激发态，并作为有机转化的光催化剂，涉及强底物键的光活化。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

In this CAREER project, funded by the Chemical Structure, Dynamics & Mechanisms B Program of the Chemistry Division, Professor Thomas S. Teets of the Department of Chemistry at the University of Houston is designing new synthetic strategies to prepare luminescent and photoactive iridium complexes. The first aim of the research develops compounds that emit blue light and may function in long-lived, high-efficiency organic light-emitting diode (LED) color displays. The second aim develops compounds that emit in the near infrared (NIR) region of the spectrum. Such compounds may be useful for biological sensing and imaging. The third aim targets compounds for photocatalysts in organic synthesis, which is important for the development of new pharmaceuticals. These research directions are complemented by an education and outreach component that aims to improve general chemistry instruction, introduce K-12 students to concepts of photochemistry, and to engage the general public in scientific learning. Professor Teets is creating an online, freely available multimedia general chemistry textbook to benefit low-income students. He also develops a K-12 lab module titled "Lighting Up Molecules" that introduces young students to the interactions of light with chemical compounds. Finally, he produces a public lecture series called "The Chemistry of Color" to introduce art enthusiasts to the chemical principles behind the creation of colors in visual art.In this project, Professor Teets studies a new class of blue phosphorescent cyclometalated iridium complexes supported by acyclic diaminocarbene and other unconventional carbene ligands. These carbene moieties destabilize interfering ligand-field states and thereby improve the quantum yield and stability of these blue-emitting compounds. In the opposite extreme of the spectrum, NIR-emitting bis-cyclometalated iridium complexes supported by electron-rich, pi-donating ancillary ligands are prepared. The electron-rich ancillary ligand destabilizes the iridium-centered Highest Occupied Molecular Orbital (HOMO), which increases the excited-state metal-to-ligand charge-transfer (MLCT) character, augments radiative rates, and improves photoluminescence quantum yield. Using similar design elements, potent visible-light photoreductants are developed. These cyclometalated iridium compounds have very reducing excited states and function as photocatalysts for organic transformations that involve photoactivation of strong substrate bonds.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.