New Tellurium-Nitrogen pi-Heterocycles: Synthesis, Structure and Potential Applications as Molecular Magnets / Conductors

新型碲氮π杂环：合成、结构和作为分子磁体/导体的潜在应用

• 批准号: 236582302
• 负责人: Professor Dr. Jens Beckmann
• 金额: --
• 依托单位: Fachbereich 02: Biologie / Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2013
• 资助国家: 德国
• 起止时间: 2012-12-31 至 2016-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/236582302?language=en
• 关键词: New; Tellurium; Nitrogen; pi; Heterocycles

It is intended to perform fundamental research of methods for synthesis, molecular and electronic structure and chemical properties of tellurium-nitrogen heterocycles - derivatives of 1,2,5-telluradiazole ring system, with special emphasis on reduction of the heterocycles into their radical anions followed by isolation of the latter in the form of thermally stable salts, together with experimental and theoretical investigation of magnetic and electrical properties of the salts for evaluation of their potential as building blocks in the design and synthesis of new functional materials - molecular magnets and / or conductors.

它的目的是进行碲-氮杂环-1，2，5-碲二唑环系统衍生物的合成方法，分子和电子结构以及化学性质的基础研究，特别强调将杂环还原为其自由基阴离子，然后以热稳定盐的形式分离后者，以及对这些盐的磁性和电学性质的实验和理论研究，以评估它们作为新功能材料-分子磁体和/或导体-的设计和合成中的构建块的潜力。

项目成果

Coordination of Halide and Chalcogenolate Anions to Heavier 1,2,5-Chalcogenadiazoles: Experiment and Theory

• DOI: 10.1021/om5006403
• 发表时间: 2014-08
• 期刊: Organometallics
• 影响因子: 2.8
• 作者: N. Semenov;A. V. Lonchakov;N. Pushkarevsky;E. Suturina;V. V. Korolev-V.;E. Lork;V. Vasiliev;S. Konchenko;J. Beckmann;N. Gritsan;A. Zibarev