Reaktive Kupfer- Bis(pyrazolyl)methan-Spezies für die Katalyse (B10#)

用于催化的反应性双(吡唑基)甲烷铜物种 (B10

• 批准号: 239000760
• 金额: --
• 依托单位: Lehrstuhl für Bioanorganische Chemie
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 财政年份: 2013
• 资助国家: 德国
• 起止时间: 2012-12-31 至 2014-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/239000760?language=en
• 关键词: Reaktive; Kupfer; Bis; pyrazolyl; methan

The most important goal of this project is the comprehensive exploration of the organometallic, coordination and bioinorganic capability of substrate activation of novel copper bis(pyrazolyl)methane complexes. The reactions are monitored time-resolved via UV/Vis spectroscopy. The starting and substrate complexes will be characterised via cyclic voltammetry, structural and theoretical studies. Special emphasis lies on the elucidation of the reaction mechanisms which have not been clarified up to now in most cases.

该项目最重要的目标是全面探索新型铜双(吡唑基)甲烷络合物的有机金属、配位能力和生物无机底物活化能力。通过UV/Vis光谱对反应进行时间分辨监测。起始络合物和底物络合物将通过循环伏安、结构和理论研究进行表征。特别强调对大多数情况下迄今尚未阐明的反应机理的解释。