Hybrid assemblies for fundamental studies of photo-induced multi-step charge transfer catalysis (C01)

用于光诱导多步电荷转移催化基础研究的混合组件（C01）

• 批准号: 240172098
• 金额: --
• 依托单位: Institut für Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/240172098?language=en
• 关键词: Hybrid; assemblies; fundamental; studies; photo

This interdisciplinary project aims to control multi-step charge transfer in hybrid assemblies for electrically and light driven oxidation of water. The hybrid systems consist of molecular catalysts for water splitting anchored to an oxide absorber film which is capable of injecting excited holes and offer sufficient stability for anchoring. Further work focusses on improved charge transfer by suitable anchoring strategies, the comprehensive study of photo-chemical activity driven by hot-polaron excitations as well as study of the reaction sequence in collaboration theory projects.

这个跨学科的项目旨在控制混合组件中的多步电荷转移，用于电和光驱动水的氧化。该混合系统由锚定到氧化物吸收膜的分子催化剂的水分解，这是能够注入激发的空穴，并提供足够的稳定性锚定。进一步的工作集中在通过合适的锚定策略改善电荷转移，热极化子激发驱动的光化学活性的综合研究以及合作理论项目中的反应序列的研究。