Does Sediment Storage Set the Pace of the Terrestrial Organic Carbon Cycle?

土壤中的碳含量大于大气中的二氧化碳含量。这意味着土壤碳储量的变化会影响气候。土壤碳还影响农业土壤的肥力，并可能影响当地的水质。鉴于对人类和环境福祉的重大影响，该提案旨在加强对土壤碳储存的理解。研究将侧重于河流的作用，河流控制着土壤在被侵蚀之前留在景观上的时间，并通过洪水影响新土壤的形成。河流也可以影响土壤中的化学条件，从而影响土壤碳。工作将在一个只含有火山岩的分水岭中进行，以避免其他岩石类型中存在的“化石”碳。主要成果包括一个新的土壤碳预测模型，对一名研究生和两名小学教师进行了地球化学方面的培训，并为小学生编写了双语教材。被认为是稳定陆地有机碳（OC）的地球化学机制都是在类似的（千年）时间尺度上演变的，与土壤和沉积物在景观上储存的时间相似。因此，利用存储过程的知识的陆地OC循环的整体视图有可能提高预测和揭示新的动态，但需要新的数据和定量模型的验证和应用。这项工作旨在通过测试与土壤，沉积物和OC储存之间的耦合相关的3个假设来解决这些具体的知识差距：（1）有机碳的年龄分布继承了河流作用对储存时间的控制，（2）储存过程通过河流对粒度分选和水文的控制影响有机碳保存的场所和生物地球化学机制，（3）冰后期景观演变通过增加景观土壤和沉积物储量，增加了陆地有机碳库的规模。这些假设将使用遥感和测量的沉积物储存估计值，基于放射性核素的沉积物和OC储存时间测定，以及OC保存的地球化学机制的元素，分子和同位素限制进行评估。该奖项反映了NSF的法定使命，并被认为值得通过使用基金会的知识价值和更广泛的影响审查标准进行评估。

The amount of carbon present in soils is larger than the amount of carbon dioxide in the atmosphere. This means changes in soil carbon storage can affect the climate. Soil carbon also affects the fertility of agricultural soil, and can influence local water quality. Given such significant implications on human and environmental wellbeing, this proposal seeks to enhance understanding of soil carbon storage. Research will focus on the role of rivers, which control the amount of time soil remains on landscapes before being eroded and which, through flooding, influence where new soil is formed. Rivers can also influence the chemical conditions in soil that affect soil carbon. Work will take place in a watershed containing only volcanic rocks to avoid the “fossil” carbon present in other rock types. Key outcomes include a new predictive model for soil carbon, the training of a graduate student and two elementary school teachers in biogeochemistry, and the development of bilingual educational materials for elementary school students. The biogeochemical mechanisms thought to stabilize terrestrial organic carbon (OC) all evolve over similar (millennial) timescales to the duration over which soil and sediment are stored on landscapes. Consequently, a holistic view of the terrestrial OC cycle that leverages knowledge of the storage processes has the potential improve predictions and reveal novel dynamics, but requires new data and quantitative models for validation and application. This work aims to address these specific knowledge gaps by testing 3 hypotheses related to the coupling between soil, sediment, and OC storage: (1) the age distribution of OC inherits its shape from the fluvial processes that regulate storage times, (2) storage processes influence the loci and biogeochemical mechanisms(s) of OC preservation via fluvial controls on grain size sorting and hydrology, and (3) post-glacial landscape evolution increases the size of the terrestrial OC reservoir via an increase in landscape soil and sediment storage. These hypotheses will be evaluated using estimates of sediment storage from remote-sensing and surveying, radionuclide-based determinations of sediment and OC storage times, as well as elemental, molecular, and isotopic constraints on the biogeochemical mechanisms of OC preservation.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.