Collaborative Research: Photomechanical Behavior in Photovoltaic Semiconductors
合作研究:光伏半导体中的光机械行为
基本信息
- 批准号:2019459
- 负责人:
- 金额:$ 26.61万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Standard Grant
- 财政年份:2020
- 资助国家:美国
- 起止时间:2020-10-01 至 2024-09-30
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
Photovoltaic semiconductors are capable of converting light into electricity. They are the principal components of solar cells that provide renewable energy from sunlight. These semiconductors tend to fail in a brittle manner, limiting their general use to small-scale applications. New evidence shows though that the mechanical behavior of photovoltaic semiconductors is sensitive to sunlight, exhibiting the potential of relative malleability under illumination. The mechanisms underlying such light-mechanical coupling effect remains elusive. This award supports fundamental research to elucidate how light-induced excitation controls the mechanical behavior of photovoltaic semiconductors. The new knowledge is expected to offer strategies to design highly stable and durable photovoltaic devices, such as solar cells, transistors, light-emitting diodes, and photodetectors, providing the basis for extensive engineering applications. This award will also offer education and training for graduate and undergraduate students in interdisciplinary areas of mechanics, materials science and engineering, and photophysics. The award will promote diversity by involving women and underrepresented minorities in research activities.The photomechanical behavior of photovoltaic semiconductors is determined by light-induced deformation mechanisms such as dislocation and twinning. In this project, a multiscale modeling and experimental framework will be used to accurately characterize the influence of photoinduced electron-hole excitation on the dislocation and twining mechanics in cadmium telluride, a prototype photovoltaic semiconductor. On the sub-atomic scale, advanced quantum mechanics simulations will be performed to determine the influence of electron-hole pair on the energy and force barriers of dislocation and twin nucleation, as well as dislocation mobility. On the atomic scale, the carrier concentration dependent mechanisms of the dislocation-dislocation and dislocation-twin interactions will be characterized using reactive force field based molecular dynamics simulations. On the mesoscale, the light-illumination effect on the stress-strain behavior will be quantified by developing an atomically-informed crystal plasticity model that incorporates dislocation slip and deformation twinning. Theoretical predictions will be validated through mechanical testing and materials characterizations using advanced experimental techniques, including nanoindentation, scanning probe microscopy, transmission electron microscopy, and electron backscatter diffraction. This work will result in a new physical picture of the deformation mechanism of photovoltaic semiconductors under light illumination, and provide a comprehensive understanding of light-mechanical coupling effects in general photovoltaic materials.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
光伏半导体能够将光转化为电。它们是太阳能电池的主要组成部分,从阳光中提供可再生能源。这些半导体往往会以脆性方式失效,从而限制了它们在小规模应用中的一般用途。新的证据表明,光伏半导体的机械行为对阳光敏感,在光照下表现出相对延展性的潜力。这种光-机械耦合效应的机制仍然是难以捉摸的。该奖项支持基础研究,以阐明光致激发如何控制光伏半导体的机械行为。新知识有望提供设计高度稳定和耐用的光伏器件的策略,如太阳能电池,晶体管,发光二极管和光电探测器,为广泛的工程应用提供基础。该奖项还将为研究生和本科生提供力学,材料科学与工程和物理学跨学科领域的教育和培训。该奖项将通过让妇女和代表性不足的少数民族参与研究活动来促进多样性。光伏半导体的光机械行为是由位错和孪生等光致变形机制决定的。在这个项目中,一个多尺度的建模和实验框架将被用来准确地描述光致电子空穴激发的影响的位错和孪晶力学碲化镉,原型光伏半导体。在亚原子尺度上,将进行先进的量子力学模拟,以确定电子空穴对对位错和孪晶成核的能量和力垒以及位错迁移率的影响。在原子尺度上,位错-位错和位错-孪晶相互作用的载流子浓度依赖机制将使用基于反应力场的分子动力学模拟来表征。在介观尺度上,光照明对应力-应变行为的影响将通过开发一个原子信息的晶体塑性模型来量化,该模型包括位错滑移和变形孪晶。理论预测将通过使用先进的实验技术,包括纳米压痕,扫描探针显微镜,透射电子显微镜和电子背散射衍射的机械测试和材料表征进行验证。这项工作将导致光伏半导体在光照射下的变形机制的新的物理图像,并提供一般光伏材料的光-机械耦合效应的全面理解。该奖项反映了NSF的法定使命,并已被认为是值得支持的评估使用基金会的智力价值和更广泛的影响审查标准。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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Victor Vasquez其他文献
The Muralla Pircada—an ancient Andean debris flow retention dam, Santa Rita B archaeological site, Chao Valley, Northern Perú
皮尔克达墙——秘鲁北部乔山谷圣丽塔 B 考古遗址的一座古老安第斯泥石流拦挡坝
- DOI:
10.1007/s10346-005-0051-7 - 发表时间:
2005-05-18 - 期刊:
- 影响因子:7.000
- 作者:
William E. Brooks;Jason C. Willett;Jonathan D. Kent;Victor Vasquez;Teresa Rosales - 通讯作者:
Teresa Rosales
Dengue, chikungunya, and Zika virus infections imported to Paris between 2009 and 2016: Characteristics and correlation with outbreaks in the French overseas territories of Guadeloupe and Martinique
- DOI:
10.1016/j.ijid.2018.05.007 - 发表时间:
2018-07-01 - 期刊:
- 影响因子:
- 作者:
Victor Vasquez;Elie Haddad;Alice Perignon;Stéphane Jaureguiberry;Ségolène Brichler;Isabelle Leparc-Goffart;Eric Caumes - 通讯作者:
Eric Caumes
Disentangling the roles of bracken fronds and litter on natural seedling recruitment in fire-disturbed tropical montane habitats
解开蕨叶和凋落物对受火灾干扰的热带山地生境中自然幼苗补充的作用
- DOI:
- 发表时间:
2024 - 期刊:
- 影响因子:3.7
- 作者:
Cecilia L. López;C. Mayta;Alfredo F. Fuentes;Mariana Villegas;Emili Antonia Jiménez;Victor Vasquez;Isabell Hensen;S. C. Gallegos - 通讯作者:
S. C. Gallegos
Native Andean potatoes (Solanum tuberosum L.): Phytonutrients in Peel, Pulp and Potato Cooking Water
原生安第斯马铃薯(Solanum tuberosum L.):皮、果肉和马铃薯烹饪水中的植物营养素
- DOI:
10.3923/ajsr.2020.44.49 - 发表时间:
2019 - 期刊:
- 影响因子:0
- 作者:
Carmen Rojas;Victor Vasquez;V. Ninaquispe;Julio Cesar Rojas;Nelson Rios;Pedro Lujan;Jesus Obregon - 通讯作者:
Jesus Obregon
Victor Vasquez的其他文献
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{{ truncateString('Victor Vasquez', 18)}}的其他基金
Collaborative Research: Integrating Nanoparticle Self-assembly into Laser/Powder-based Additive Manufacturing of Multimodal Metallic Materials
合作研究:将纳米粒子自组装集成到多模态金属材料的激光/粉末增材制造中
- 批准号:
2231077 - 财政年份:2023
- 资助金额:
$ 26.61万 - 项目类别:
Standard Grant
Collaborative Research: Manufacturing of Low-cost Titanium Alloys by Tuning Highly-indexed Deformation Twinning
合作研究:通过调整高指数变形孪晶制造低成本钛合金
- 批准号:
2122272 - 财政年份:2021
- 资助金额:
$ 26.61万 - 项目类别:
Continuing Grant
Collaborative Research: Design and Advanced Manufacturing of Hexaboride High Entropy Ceramics
合作研究:六硼化物高熵陶瓷的设计与先进制造
- 批准号:
2016261 - 财政年份:2020
- 资助金额:
$ 26.61万 - 项目类别:
Standard Grant
SGER: Model Uncertainty and Robustness in Nonlinear Model Predictive Control for Biomedical Applications
SGER:生物医学应用非线性模型预测控制中的模型不确定性和鲁棒性
- 批准号:
0328247 - 财政年份:2003
- 资助金额:
$ 26.61万 - 项目类别:
Standard Grant
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