Collaborative Research: Understanding and Tailoring the Anode-Electrolyte Interfacial Layers on the Stabilization of Lithium Metal Electrode

合作研究：理解和定制阳极-电解质界面层对锂金属电极稳定性的影响

• 批准号: 2038083
• 负责人: Ye Cao
• 金额: $ 19.23万
• 依托单位: University of Texas at Arlington
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2021
• 资助国家: 美国
• 起止时间: 2021-03-01 至 2025-02-28
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2038083&HistoricalAwards=false
• 关键词: Collaborative; Research; Understanding; Tailoring; Anode

Metallic lithium (Li) is considered as one of the promising next-generation anode materials to replace conventional graphite in Li-ion batteries because of its high theoretical specific energy capacity and low reduction potential. However, dendrite growth on the electrode and unstable solid-electrolyte interphase (SEI) formation have created safety concerns in Li batteries and hindered practical applications. Introducing an artificial protective layer on the Li metal electrode is an effective strategy to stabilize the Li electrode, yet how this protective layer interacts with the electrochemical process of Li metal anode is not well understood. This project will integrate experiments and simulations to understand how the physical and chemical properties of the protective layer affect the electrochemical performance of the Li metal electrode. The fundamental knowledge gained will guide development of novel Li metal electrodes with high performance and improved safety for electric vehicles and other high-energy-density electrical storage devices. The project will also involve the education of graduate, undergraduate students, and K-12 students by course development, summer camp, and outreach activities in local museums.The overarching goal of this project is to develop a new understanding of the key physical and chemical properties of the protective layer that leads to stable charge/discharge processes of the Li metal electrode. The state-of-the-art guideline is insufficient, and the model only considers the influences of the limited mechanical properties of the protective layer on the stabilization of the Li metal electrode. In this project, by an effective integration of experimental synthesis, characterization and phase-field simulations, a new understanding will be generated on electrochemistry and deformation/failure mechanism of suppressing dendrites, including mass transport, electric potential, stress, and deformation. The research goal will be reached by working on several objectives: (1) Effect of mechanical properties of the protective layer on the suppression of Li dendrite growth; (2) Effect of ionic mass transfer behaviors of the protective layer on the stabilization of the Li metal electrode; (3) Novel protective layer on Li metal for the high-performance assembled cells. The elucidated correlation between physical and chemical properties of the protective layer, and the electrochemical processes of the electrode is expected to open pathways for the novel design and fabrication of Li metal electrodes, leading to stable and high-performance next-generation energy storage devices.This project is jointly funded by the CBET Electrochemical Systems program and the Established Program to Stimulate Competitive Research (EPSCoR).This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

金属锂（​​Li）因其高理论比能量和低还原电位而被认为是有前途的下一代锂离子电池负极材料之一，可替代传统石墨。然而，电极上的枝晶生长和不稳定的固体电解质界面（SEI）的形成引起了锂电池的安全问题并阻碍了实际应用。在锂金属电极上引入人工保护层是稳定锂电极的有效策略，但该保护层如何与锂金属阳极的电化学过程相互作用尚不清楚。该项目将结合实验和模拟来了解保护层的物理和化学性质如何影响锂金属电极的电化学性能。所获得的基础知识将指导开发具有高性能和更高安全性的新型锂金属电极，用于电动汽车和其他高能量密度电存储设备。该项目还将通过课程开发、夏令营和当地博物馆的外展活动，对研究生、本科生和 K-12 学生进行教育。该项目的总体目标是对保护层的关键物理和化学特性产生新的认识，从而实现锂金属电极稳定的充电/放电过程。最先进的指南是不够的，并且该模型仅考虑了保护层有限的机械性能对锂金属电极稳定性的影响。在该项目中，通过实验合成、表征和相场模拟的有效结合，将对抑制枝晶的电化学和变形/失效机制（包括传质、电势、应力和变形）产生新的认识。研究目标将通过以下几个目标来实现：（1）保护层力学性能对抑制锂枝晶生长的影响； (2)保护层离子传质行为对锂金属电极稳定性的影响； (3)用于高性能组装电池的锂金属上的新型保护层。阐明保护层的物理和化学性质与电极的电化学过程之间的相关性有望为锂金属电极的新颖设计和制造开辟途径，从而产生稳定和高性能的下一代储能设备。该项目由 CBET 电化学系统计划和刺激竞争研究既定计划 (EPSCoR) 联合资助。该奖项反映了 NSF 的 法定使命，并通过使用基金会的智力优点和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Phase-Field Simulation and Machine Learning Study of the Effects of Elastic and Plastic Properties of Electrodes and Solid Polymer Electrolytes on the Suppression of Li Dendrite Growth

电极和固体聚合物电解质的弹塑性特性对抑制锂枝晶生长影响的相场模拟和机器学习研究

• DOI: 10.1021/acsami.2c03000
• 发表时间: 2022
• 期刊: ACS Applied Materials & Interfaces
• 影响因子: 9.5
• 作者: Ren, Yao;Zhang, Kena;Zhou, Yue;Cao, Ye
• 通讯作者: Cao, Ye

Decreasing Water Activity Using the Tetrahydrofuran Electrolyte Additive for Highly Reversible Aqueous Zinc Metal Batteries

• DOI: 10.1021/acsami.2c17714
• 发表时间: 2023-01-25
• 期刊: ACS APPLIED MATERIALS & INTERFACES
• 影响因子: 9.5
• 作者: He, Wei;Ren, Yao;Zhou, Yue
• 通讯作者: Zhou, Yue