CAREER: An Integrated Experimental-Theoretical Framework for Understanding the Multiscale Mechanical Response of Rock-Reactive Brine Interactions

该学院的早期职业发展（CAREER）计划将支持研究，以了解和阐明岩石与反应性盐水相互作用时的机械性能的演变。岩石和活性盐水在恶劣环境中的相互作用在几个应用中起着重要作用，例如斜坡和废弃地下洞穴的稳定性，碳封存，增强地热系统，储层刺激和污染物运输。通过了解岩石-反应性盐水相互作用如何影响岩石的力学性质，将有可能开发出更现实的物理化学模型，这些模型对于预测岩石力学稳定性和定量解释地球物理监测数据至关重要。然而，挑战来自于复杂的多尺度和岩石的异质性和岩石反应性盐水相互作用的复杂性，使得传统的实验和建模技术对这个问题无效。该项目使用新颖的多尺度实验和理论来揭示岩石在暴露于活性盐水时力学性质如何变化的起源。该项目的成果将通过提高基础设施系统的弹性以及能源和资源效率来服务于社会。该项目还有一个全面的教育和外联计划，以扩大在STEM中代表性不足的少数群体的参与，并加强化学和岩石与流体相互作用力学方面的教育。这是通过从事传统上代表性不足的高中生，增加公众对岩石和流体相互作用的影响的理解，并在合作和跨学科的研究活动中教育研究生和本科生。主要活动是招募代表性不足的本科生，并通过一个名为“岩石和流体”的扩展外展计划吸引高中生。本CAREER计划的目标是（1）了解化学-力学岩石-反应性盐水相互作用对岩石的微观结构/形态结构和成分性质的影响：（2）确定多尺度下化学-力学载荷与地质力学响应之间的关系;和（3）确定岩石内的应力/应变分布，作为其随时间变化的微观结构的函数，由化学和机械效应引起，使用物理化学孔隙尺度模型。研究方法包括个别岩石成分的微观尺度化学-力学表征，宏观尺度力学评估，以及岩石样品在高温高压条件下暴露于活性盐水之前和之后的微观结构表征;以及开发孔隙尺度模型，以深入了解受化学-力学相互作用影响的岩石随时间变化的力学和变形行为。研究结果将导致基于物理的监测数据的解释和提高岩石的机械稳定性。该奖项反映了NSF的法定使命，并已被认为是值得通过使用基金会的智力价值和更广泛的影响审查标准进行评估的支持。

This Faculty Early Career Development (CAREER) program will support research to understand and elucidate the evolution of the mechanical properties of rocks when interacting with reactive brine. The interaction between rocks and reactive brine in harsh environments plays an important role in several applications, such as stability of slopes and abandoned underground caves, carbon sequestration, enhanced geothermal systems, reservoir stimulation, and contaminant transport. By understanding how rock-reactive brine interaction affects the mechanical properties of rocks, it will be possible to develop more realistic physical-chemical models that are critical for predicting rock mechanical stability and for quantitatively interpreting geophysical monitoring data. However, the challenge comes from the complex multiscale and heterogeneous nature of rocks and the complexity of rock-reactive brine interactions, making the traditional experimental and modeling techniques ineffective for this problem. This project uses novel multiscale experiments and theory to reveal the origins of how mechanical properties of rocks change when exposed to reactive brine. The outcomes of this project will serve the society by enhancing infrastructure system resiliency, and energy and resource efficiency. This project also has a comprehensive education and outreach plan to broaden the participation of underrepresented minorities in STEM and enhance education in chemistry and mechanics of rock and fluid interaction. This is done through engaging traditionally underrepresented high school students, increasing the general public’s understanding of the impact of rock and fluid interaction, and educating graduate and undergraduate students in collaborative and interdisciplinary research activities. The main activity is recruiting underrepresented undergraduates and engaging high school students via an extended outreach program entitled “Rocks and Fluids.” The objectives of this CAREER program are to (1) Understand the effect of chemo-mechanical rock-reactive brine interaction on the microstructural/morphological texture and compositional properties of rocks; (2) Determine the relationship between chemo-mechanical loading and geomechanical response at multiple scales; and (3) Determine the stress/strain distribution within the rock as a function of its time-evolving microstructure, induced by chemical and mechanical effects, using a physical-chemical pore-scale model. The research approaches include micro-scale chemo-mechanical characterization of individual rock constituents, macro-scale mechanical assessment, and microstructural characterization of rock samples before and after exposure to reactive brine at high temperature and pressure conditions; and development of a pore-scale model to gain insight into time-dependent mechanical and deformational behavior of rocks influenced by chemo-mechanical interactions. Research findings will lead to physics-based interpretation of monitoring data and enhancement of the mechanical stability rocks.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.