Collaborative Research: US GEOTRACES GP17-OCE and GP17-ANT: Thorium-230, Thorium-232 and Protactinium-231 tracers of trace element supply and removal

国际GEOTRACES项目的目标是了解海洋中微量化学元素及其同位素的分布。许多微量元素是生命所必需的，被认为限制了海洋大部分地区的生物生产力。这种限制反过来又在一定程度上控制了海洋支持其他海洋生物的能力，以及海洋从大气中吸收二氧化碳的能力。该项目将对南太平洋和阿蒙森海提供和去除微量元素的过程提供限制，这些过程目前尚未得到很好的量化。作为这项工作的一部分，将测量天然存在的放射性同位素，如钍-230和镤-231，它们可以作为替代品，提供有关提供铁和其他微量营养元素的过程以及这些过程的速率的关键信息。同位素钍-232还将被用作通过气溶胶粉尘沉积和沿海沉积物添加到海洋中的元素供应的示踪剂。这些速率和通量可以用来提高我们对全球碳循环中至关重要的微量营养铁和碳沉降通量的理解。通过本科和研究生教学、海洋科学碗等社区活动以及国际GEOTRACES项目的其他努力，将实现外联和更广泛的影响。该项目将为四个合作实验室（南密西西比大学、明尼苏达大学、哥伦比亚大学的Lamont-Doherty和加州理工学院）提供支持，在南太平洋进行两次美国GEOTRACES巡航，称为GP17 （GP17- oce从塔希提岛向南行驶到边缘海冰区，GP17- ant专注于阿蒙森边缘）。pi将测量Th-230和Pa-231的溶解浓度和颗粒浓度。此外，他们将测量溶解和颗粒Th-232浓度，并分析有限数量的气溶胶样品，气溶胶渗滤液，胶体大小分数和这些放射性核素的表面沉积物。它们将用于量化微量元素的供应，包括阿蒙森海冰川融水泵的沉积物输入和世界上最低粉尘输入地区之一的大气粉尘输入。此外，该团队将能够量化微量元素的去除，包括碳的下沉颗粒通量，以及微量元素，以及可变颗粒组成体系的清除特性。这些目标也有助于评估Th和Pa作为关键的古海洋学指标。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

The goal of the international GEOTRACES program is to understand the distributions of trace chemical elements and their isotopes in the oceans. Many trace elements are essential for life and are thought to limit biological productivity throughout much of the ocean. This limitation, in turn, partly controls the ability of the ocean to support other marine life as well as the ocean's capacity to absorb carbon dioxide from the atmosphere. This project will provide constraints on the processes that supply and remove trace elements in the South Pacific Ocean and Amundsen Sea which are currently not well quantified. Naturally occurring radioactive isotopes such as thorium-230 and protactinium-231, which will be measured as a part of this work, can be utilized as proxies to provide critical information about the processes that supply iron and other micronutrient elements, as well as the rates of those processes. The isotope thorium-232 will also be utilized as a tracer of the supply of elements that are added to the ocean through the deposition of aerosol dust and from coastal sediments. These rates and fluxes can be used to improve our understanding of the micro-nutrient iron and the sinking fluxes of carbon which are both critical in the global carbon cycle. Outreach and broader impacts will be achieved through undergraduate and graduate teaching, community events such as the Ocean Sciences Bowl and other efforts through the international GEOTRACES program. This project will provide support for four collaborating labs (University of Southern Mississippi, University of Minnesota, Lamont-Doherty at Columbia University and CalTech) to undertake measurements on two US GEOTRACES cruises in the South Pacific, known as GP17 (GP17-OCE running from Tahiti south to the marginal sea ice zone and GP17-ANT focusing on the Amundsen margin). The PIs will measure dissolved and particulate concentrations of Th-230 and Pa-231. In addition, they will measure dissolved and particulate Th-232 concentrations and analyze a limited number of aerosol samples, aerosol leachates, colloidal size fractions and surface sediments for these radionuclides. They will be used to quantify trace element supply, including sedimentary inputs from the Amundsen Sea’s glacial meltwater pump and atmospheric dust inputs in one of the world’s lowest dust input regions. Additionally, the team will be able to quantify trace element removal, including sinking particulate fluxes for carbon, as well as trace elements, and scavenging characteristics of variable particle composition regimes. These goals also contribute to assessing Th and Pa as key palaeoceanographic proxies.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.