Collaborative Proposal: How to Gel Oil (or Water) in an Immiscible Oil-Water Mixture: A Systematic Study of Phase-Selective Gelation

大家都知道油和水不能混合。该奖项将研究如何将这些液体之一选择性地转化为凝胶-这一过程被称为相选择性凝胶化。为了诱导这种凝胶化，将合成分子，这些分子将找到进入油层或水层的方式，然后在那里进行“自组装”。自组装意味着分子将自发地结合并形成纳米级尺寸的结构-在这种情况下，长纤维。反过来，纳米纤维将相互缠绕，从而将液体转化为糊状材料（具有番茄酱或发胶的稠度）。这将是第一个系统的相选择性凝胶化研究。该奖项的见解可以帮助设计新材料来清理石油泄漏或修复石油污染的地下水。该奖项的重点将是相选择性凝胶化现象背后的基础科学，目标将是开发连接分子结构，界面性质和凝胶结构/流变学的设计规则。将合成一系列两亲分子，并研究它们在混合物中使油相或水相凝胶化的能力。作为相选择性胶凝剂的分子的关键标准是：（a）它不应使油-水混合物增溶;和（B）它也不应在任一相中明显增溶。假设这种凝胶化可以通过在两亲分子之间的非共价相互作用如头部基团之间的氢键以及尾部之间的π-π和货车范德华相互作用的正确平衡来实现。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

Everyone knows that oil and water do not mix. This award will study how one of these liquids can be selectively converted into a gel – a process that is termed phase-selective gelation. To induce such gelation, molecules will be synthesized that will find their way into either the oil or the water layer and then undergo ‘self-assembly’ there. Self-assembly implies that the molecules will spontaneously join and form structures – in this case, long fibers – with nanoscale sizes. In turn, the nanofibers will entangle with each other and thus convert the liquid into a paste-like material (with the consistency of ketchup or hair gel). This will be the first systematic study on phase-selective gelation. The insights from this award could help design new materials to clean-up oil spills or to remediate oil-contaminated ground water. The focus of this award will be on the fundamental science behind the phenomenon of phase-selective gelation, and the goal will be to develop design rules connecting molecular structure, interfacial properties, and gel structure/rheology. A range of amphiphilic molecules will be synthesized and their ability to gel either the oil or water phase in a mixture will be studied. Key criteria for a molecule to be a phase-selective gelator are: (a) it should not emulsify the oil-water mixture; and (b) it should also not get appreciably solubilized in either of the phases. The hypothesis is that such gelation can be accomplished by striking the right balance of non-covalent interactions between the amphiphilic molecules such as hydrogen-bonding between the head groups as well as pi-pi and van der Waals interactions between the tails. The proposed research will also be integrated with educational, mentoring, and outreach activities at the collaborating institutions.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.