Covalent Polymer Mechanochemistry
共价聚合物机械化学
基本信息
- 批准号:2304884
- 负责人:
- 金额:$ 80万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Standard Grant
- 财政年份:2023
- 资助国家:美国
- 起止时间:2023-09-01 至 2027-08-31
- 项目状态:未结题
- 来源:
- 关键词:
项目摘要
With the support from the Macromolecular, Supramolecular and Nanochemistry Program of the NSF Chemistry Division, Professor Stephen Craig at Duke University is learning how to dictate the rates and outcomes of chemical reactions that are accelerated by an applied mechanical force. Organic polymeric materials, or plastics, break down due to the mechanical forces they experience during their use cycles. The mechanical degradation of polymers limits their use in lightweight structural materials, consumer products, and biomedical applications. Reactions that are sensitive to a coupled force therefore impact multiple aspects of materials design, including the macroscopic failure and mechanical limitations of current polymeric materials. In addition, mechanically responsive functional groups might serve as the critical elements in new stress-responsive and self-healing polymeric materials. Professor Craig’s studies will provide insight into how the macroscopic mechanical forces experienced by polymers during use can be effectively channeled into desired chemical responses, providing a foundation for new classes of polymers. Broader impacts of the project include: (1) developing active learning modules and associated laboratory experiences in introductory chemistry and through coupled undergraduate and high school research experiences; (2) broadening the participation of underrepresented groups by engaging and recruiting young scientists early in their scientific careers, before the onset of disproportionate attrition from the sciences; (3) disseminating the results of the research broadly; and, (4) addressing fundamental questions of molecular behavior in a manner that will have an impact on a broad range of fields including polymer chemistry, physical organic chemistry, and self-healing and stress-responsive materials. The overarching technical objective is to lay a quantitative foundation for mechanochemical kinetics by employing state-of-the-art physical measurements and developing new methods for quantitation. The research plan includes the direct, experimental characterization and quantification of the effect of mechanical forces on covalent reactions triggered along overstretched polymer backbones. Because mechanical force, unlike conventional forms of energy input such as heat or light, is directional, the coupling between mechanical force and reactivity is expected to provide insights into the structure of transition states and the shapes of reaction potential energy surfaces. Despite its importance, however, quantitative measures of the effect of force on chemical reactions are rare. The proposed work will further develop a novel approach to quantifying mechanochemical reactivity: pulling on single molecules of muti-mechanophore, non-scissile polymers with an atomic force microscope. Models for the observed mechanochemical activity should permit a quantitative assessment of reactivity, and of the influence of external factors such as the surrounding environment and light-induced changes upon molecular structure.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
在美国国家科学基金会化学部大分子、超分子和纳米化学项目的支持下,杜克大学的斯蒂芬·克雷格教授正在学习如何控制被施加的机械力加速的化学反应的速率和结果。有机聚合物材料,或塑料,由于它们在使用周期中经历的机械力而分解。聚合物的机械降解限制了它们在轻质结构材料、消费品和生物医学应用中的应用。因此,对耦合力敏感的反应会影响材料设计的多个方面,包括当前聚合物材料的宏观失效和机械限制。此外,机械响应官能团可能成为新型应力响应和自修复聚合物材料的关键元素。Craig教授的研究将深入了解聚合物在使用过程中所经历的宏观机械力如何有效地转化为所需的化学反应,为新型聚合物提供基础。该项目更广泛的影响包括:(1)通过结合本科和高中的研究经验,开发主动学习模块和相关的化学入门实验室经验;(2)在科学领域出现不成比例的人员流失之前,通过在年轻科学家的科学职业生涯早期吸引和招募他们,扩大代表性不足群体的参与;(3)广泛传播研究成果;(4)解决分子行为的基本问题,这将对包括聚合物化学、物理有机化学、自愈和应力响应材料在内的广泛领域产生影响。总体技术目标是通过采用最先进的物理测量和开发新的定量方法,为机械化学动力学奠定定量基础。研究计划包括直接、实验表征和定量机械力对沿拉伸聚合物骨架引发的共价反应的影响。由于机械力不同于传统形式的能量输入,如热或光,是定向的,因此机械力和反应性之间的耦合有望提供对过渡态结构和反应势能面形状的见解。然而,尽管力对化学反应的影响很重要,但对它的定量测量却很少。提出的工作将进一步发展一种量化机械化学反应性的新方法:用原子力显微镜拉多机械团,非剪切聚合物的单分子。所观察到的机械化学活性的模型应允许对反应性和外部因素(如周围环境和光引起的分子结构变化)的影响进行定量评估。该奖项反映了美国国家科学基金会的法定使命,并通过使用基金会的知识价值和更广泛的影响审查标准进行评估,被认为值得支持。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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Stephen Craig其他文献
Impact of using fasting plasma glucose and HbA1c instead of OGTT as a screening tool for gestational diabetes: a retrospective study
使用空腹血糖和 HbA1c 代替 OGTT 作为妊娠期糖尿病筛查工具的影响:一项回顾性研究
- DOI:
10.1002/pdi.2434 - 发表时间:
2023 - 期刊:
- 影响因子:0.6
- 作者:
Hannah Cooke;Stephen Craig;H. Kahal;F. Talbot;K. Lonnen - 通讯作者:
K. Lonnen
Stephen Craig的其他文献
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{{ truncateString('Stephen Craig', 18)}}的其他基金
NSF-BSF: Emergent Rheology of Blends Containing Supramolecular Polymers
NSF-BSF:含有超分子聚合物的共混物的新兴流变学
- 批准号:
2409077 - 财政年份:2024
- 资助金额:
$ 80万 - 项目类别:
Standard Grant
Collaborative Research: CAS: Mechanochemistry of Metallocenes
合作研究:CAS:茂金属机械化学
- 批准号:
2203396 - 财政年份:2022
- 资助金额:
$ 80万 - 项目类别:
Standard Grant
NSF Center for the Chemistry of Molecularly Optimized Networks
NSF 分子优化网络化学中心
- 批准号:
2116298 - 财政年份:2021
- 资助金额:
$ 80万 - 项目类别:
Cooperative Agreement
RAPID: Collaborative Research: Augmenting Mucosal Gels with Associating Brush Polymers to Prevent COVID19 Infection
RAPID:合作研究:用缔合刷状聚合物增强粘膜凝胶以预防新冠病毒感染
- 批准号:
2029760 - 财政年份:2020
- 资助金额:
$ 80万 - 项目类别:
Standard Grant
Collaborative Research: Mechanochemistry of Metallocenes
合作研究:茂金属的机械化学
- 批准号:
1904016 - 财政年份:2019
- 资助金额:
$ 80万 - 项目类别:
Standard Grant
CCI Phase I: NSF Center for the Chemistry of Molecularly Optimized Networks
CCI 第一阶段:NSF 分子优化网络化学中心
- 批准号:
1832256 - 财政年份:2018
- 资助金额:
$ 80万 - 项目类别:
Standard Grant
Travel Support for Student and Speaker Participation at the Fifth International Conference on Self-Healing Materials; Duke University; Durham, North Carolina; June 22-24, 2015
为学生和演讲者参加第五届国际自愈材料会议提供差旅支持;
- 批准号:
1522581 - 财政年份:2015
- 资助金额:
$ 80万 - 项目类别:
Standard Grant
REU Site: Chemistry and Applications of Smart Molecules and Materials at Duke University
REU 网站:杜克大学智能分子和材料的化学与应用
- 批准号:
1062607 - 财政年份:2011
- 资助金额:
$ 80万 - 项目类别:
Continuing Grant
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- 批准年份:2011
- 资助金额:25.0 万元
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