CAREER: Illuminating molecular-level effects in new plant-based nanocomposites for additive manufacturing by stereolithography

职业：通过立体光刻阐明用于增材制造的新型植物基纳米复合材料的分子水平效应

• 批准号: 2337946
• 负责人: Stephen Chmely
• 金额: $ 62.53万
• 依托单位: Pennsylvania State Univ University Park
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2024
• 资助国家: 美国
• 起止时间: 2024-08-01 至 2029-07-31
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2337946&HistoricalAwards=false
• 关键词: CAREER; Illuminating; molecular; level; effects

NON-TECHNICAL SUMMARYPlants are remarkable organisms. They are towering, sunlight-driven factories that use carbon dioxide, water, and soil nutrients to create all the materials they need to survive, including the factory itself! While many human-made factories are constructed using concrete, plants use long molecules called polymers to create supporting structures. These structures allow a plant to stand up and reach out for sunlight, move water and nutrients between its organs, and protect itself and its offspring. One of these polymers is called lignin, and it functions like the cement in concrete; it is a sort of glue that holds everything together. It also has a chemical structure that is very similar to many of the plastics that people use in everyday life. Therefore, lignin could be used to make new plastics, including those used for 3D printing. Using lignin to 3D print objects would be like how plants use lignin to manufacture their leaves, stems, roots, and seeds. Also, since plants are a renewable resource, plastics made from them would also be renewable, which is the opposite of current non-renewable plastics that are made from crude oil. Finally, since plants use carbon dioxide to make lignin, growing new plants to make new plastics would reduce the amount of carbon dioxide in the atmosphere, which could lessen its effect on climate change. The goal of this project is to learn how to control the structure of lignin taken from plants and use it to create new materials for 3D printing. New chemistry methods to extract, modify, and use lignin will be explored. The principal investigator will also study how using lignin and other plant polymers could lessen the effects of climate change and how using them could help people in rural communities get good jobs related to these new renewable materials. In addition, the research plan will be augmented by enriching undergraduate education at the intersection of polymer science and sustainability, supporting undergraduate research opportunities related to sustainability, and disseminating cutting edge research principles to K12 students through Research Experiences for Teachers program.TECHNICAL SUMMARYThe overarching goals of this CAREER plan are to (1) develop 3D printable composite resins consisting of suitably modified nanocellulose and lignin, (2) use this research as a platform to introduce students to both fundamental principles of polymer science and issues of social justice and sustainability that underpin renewable bioproducts, and (3) contribute to global efforts to diminish the effects of anthropogenic climate change by reducing the concentration of atmospheric carbon. The proposed CAREER plan will advance knowledge and understanding in several fields, including green engineering, synthetic chemistry, and polymer science and engineering. The aims include (1) establishing approaches to control the oxidation state of aliphatic carbons in lignin during fractionation and upgrading, (2) developing techniques to control lignin structure and function as a photopolymerizable polymer matrix, and (3) identifying methods to blend modified lignin feedstocks to create new stereolithography resins. These activities explore transformative concepts, including producing entirely renewable biocomposite resins for 3D printing. In addition, the research plan will be augmented by (1) enriching undergraduate education at the intersection of polymer science and sustainability, (2) supporting undergraduate research opportunities related to sustainability and “Drawdown,” and (3) disseminating cutting edge research principles to K12 students through Research Experiences for Teachers.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术性的总和植物是非凡的有机体。它们是高耸的、阳光驱动的工厂，利用二氧化碳、水和土壤养分来创造它们生存所需的所有材料，包括工厂本身！虽然许多人造工厂是用混凝土建造的，但植物使用被称为聚合物的长分子来创建支撑结构。这些结构允许植物站立并伸手吸收阳光，在其器官之间转移水分和营养，并保护自己和后代。其中一种聚合物被称为木质素，它的功能就像混凝土中的水泥；它是一种将一切结合在一起的胶水。它的化学结构也与人们日常生活中使用的许多塑料非常相似。因此，木质素可以用来制造新的塑料，包括用于3D打印的塑料。将木质素用于3D打印对象类似于植物如何使用木质素来制造它们的叶、茎、根和种子。此外，由于植物是一种可再生资源，由它们制成的塑料也是可再生的，这与目前由原油制成的不可再生塑料相反。最后，由于植物使用二氧化碳来制造木质素，种植新的植物来制造新的塑料将减少大气中的二氧化碳数量，这可能会减轻其对气候变化的影响。这个项目的目标是学习如何控制从植物中提取的木质素的结构，并使用它来创造3D打印的新材料。将探索提取、修饰和利用木质素的新化学方法。首席研究员还将研究使用木质素和其他植物聚合物如何减轻气候变化的影响，以及使用它们如何帮助农村社区的人们获得与这些新的可再生材料相关的好工作。此外，研究计划将通过丰富聚合物科学和可持续发展交叉学科的本科生教育，支持与可持续发展相关的本科生研究机会，并通过教师研究经验计划向K12学生传播尖端研究原理来扩大研究计划。技术总结本职业计划的总体目标是(1)开发由适当改性的纳米纤维素和木质素组成的3D可打印复合树脂，(2)将本研究作为一个平台，向学生介绍聚合物科学的基本原理以及支撑可再生生物产品的社会正义和可持续发展问题，以及(3)通过减少大气碳浓度，为全球减少人为气候变化的影响做出贡献。拟议的职业计划将促进几个领域的知识和理解，包括绿色工程、合成化学和聚合物科学与工程。其目的包括：(1)建立控制木质素中脂肪碳氧化状态的方法；(2)开发控制木素结构和作为光聚合聚合物基质的技术；(3)确定混合改性木质素原料的方法，以创造新的光固化树脂。这些活动探索了变革性的概念，包括为3D打印生产完全可再生的生物复合树脂。此外，研究计划将通过(1)丰富聚合物科学和可持续发展交叉学科的本科生教育，(2)支持与可持续发展和“下降”相关的本科生研究机会，以及(3)通过教师研究经验向K12学生传播尖端研究原理。该奖项反映了NSF的法定使命，并通过使用基金会的智力优势和更广泛的影响审查标准进行评估，被认为值得支持。