Tailor-Made Sequence-Controlled Polymer-Dye-Conjugates for Controlling Exciton Dynamics (A04)

该项目将开发一种序列定义的合成路线，以创建高度可剪裁的刚性大分子。新的合成策略将允许创建序列定义的棒状大分子，作为第一个例子，将被用于理解和优化用于能量转换的功能聚合物的光物理性质。这个项目与其他项目的不同之处在于，它创建的功能是物理性质的，而不是化学性质的。然而，这一功能是通过开发化学控制来实现的，该控制旨在相对于刚性聚合物主干在空间中精确定位功能分子。

This project will develop a sequence-defined synthesis route to create highly-tailorable rigid macromolecules. New synthetic strategies will allow the creation of sequence-defined rod-like macromolecules that will be used, as a first example, to understand and optimise the photophysical properties of functional polymers for energy conversion. This project is distinct from the others in that the functionality it creates is of a physical rather than chemical nature. However, this functionality is achieved by the chemical control developed to precisely locate functional molecules in space relative to the rigid polymer backbone.