Development of liquid catalysts exhibiting ionic conductivity

具有离子导电性的液体催化剂的开发

• 批准号: 24655126
• 负责人: MOCHIDA Tomoyuki
• 金额: $ 2.58万
• 依托单位: Kobe University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Challenging Exploratory Research
• 财政年份: 2012
• 资助国家: 日本
• 起止时间: 2012-04-01 至 2014-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-24655126/
• 关键词: イオン液体; 金属錯体; 触媒; メタロセン

This study aims at developing liquid catalysts having ionic conductivity. By applying the molecular design that we developed earlier, a variety of ionic liquids were prepared from metal complexes having catalytic activities.First, Ru-containing ionic liquids were prepared from arene-Ru complexes bearing various bidentate ligands. These salts exhibited high catalytic activities toward the oxidation of alcohols, but the complexes were found to undergo gradual decomposition during the reaction. Second, Cu-containing ionic liquids were prepared from Cu complexes bearing tripod ligands. Ligands containing alkyl-imidazole moieties were designed. Cu(I) complexes were highly unstable; however, Cu(II) complexes were isolated as solids or highly viscous liquids.

本研究旨在开发具有离子导电性的液体催化剂。通过应用我们早期开发的分子设计，由具有催化活性的金属配合物制备了多种离子液体。首先，由带有各种双齿配体的芳烃-Ru配合物制备了含Ru离子液体。这些盐对醇的氧化表现出高催化活性，但发现络合物在反应过程中逐渐分解。其次，由带有三脚配体的铜络合物制备含铜离子液体。设计了含有烷基咪唑部分的配体。 Cu(I) 配合物高度不稳定；然而，Cu(II) 配合物以固体或高粘度液体的形式分离出来。

项目成果

ルテノセン系イオン液体の熱物性および反応性

茂铁基离子液体的热物理性质和反应活性

• 发表时间: 2012
• 作者: Y. Funasako;M. Nosho;T. Mochida;安部健一,稲垣尭,持田智行;森翔大朗,持田智行
• 通讯作者: 森翔大朗,持田智行

アレーンルテニウム錯体からなるイオン液体の熱物性および触媒活性

芳烃钌配合物离子液体的热性能及催化活性

• 发表时间: 2012
• 作者: Y. Funasako;M. Nosho;T. Mochida;安部健一,稲垣尭,持田智行
• 通讯作者: 安部健一,稲垣尭,持田智行