„Inner-pore“-tethered tetraaza-ruthenium-complexes for the directed hydrogen-autotransfer catalysis (B01+)

用于定向氢自转移催化的“内孔”束缚四氮杂钌配合物 (B01)

• 批准号: 406658540
• 金额: --
• 依托单位: Professur für Organische Chemie I
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 财政年份: 2018
• 资助国家: 德国
• 起止时间: 2017-12-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/406658540?language=en
• 关键词: Inner; pore; tethered; tetraaza; ruthenium

In project B1 a (NNNN)Ru-complex will be linked to the inner pore-wall of materials from projects A1-A4 and A6. The catalytic performance of the hybrid materials will be analyzed as a function of pore diameter, shape, and geometry versus linker lengths and hydrophilicity of the material. H2-autotransfer catalysis processes are intercepted transferhydrogenation processes; hence, an acceleration of the interception process, i.e. the condensation between ketone and amine, through fine-tuning of all the aforementioned parameters is expected. Cooperations with PIs from spectroscopy and theory (projects C1-C6) will aid to understand pore-specific confinement effects on H2-autotransfer catalysis.

在项目B1中，（NNNN）Ru络合物将连接到项目A1-A4和A6的材料的内孔壁。杂化材料的催化性能将作为孔径、形状和几何形状与连接体长度和材料亲水性的函数进行分析。H2-自动转移催化过程是被拦截的转移氢化过程;因此，预期通过微调所有上述参数来加速拦截过程，即酮和胺之间的缩合。与光谱学和理论（项目C1-C6）的PI合作将有助于理解H2-自动转移催化的孔特异性限制效应。