Synthesis, characterization and reactivity studies of ozonido and oxido complexes of iron, nickel, cobalt and copper ions

该项目的主要目标是过渡金属（铁、镍、钴和铜）臭氧配合物及其相应的氧化配合物的合成和表征。它们在有机底物氧化方面的反应性将被研究。应完成臭氧配合物的稳定，使其晶体学表征。这可能导致未来的应用（原位）在有机合成。长期目标将是固定氧化或臭氧配合物（例如在二氧化硅中），使其在催化氧化反应中的实际应用中有用。

Main goal of the project is the synthesis and characterization of transition metal (iron, nickel, cobalt and copper) ozonido complexes and furthermore corresponding oxido complexes. Their reactivity in regard to oxidation of organic substrates will be investigated. Stabilization of ozonido complexes should be accomplished to allow their crystallographic characterization. This could lead to a future application (in situ) in organic synthesis. A long term goal will be the immobilization of either oxido or ozonido complexes (e. g. in silica) to make them useful for practical applications in catalytic oxidation reactions.