Synthesis, characterization and reactivity studies of ozonido and oxido complexes of iron, nickel, cobalt and copper ions

铁、镍、钴和铜离子的臭氧和氧化络合物的合成、表征和反应性研究

• 批准号: 429317549
• 负责人: Professor Dr. Siegfried Schindler
• 金额: --
• 依托单位: Institut für Anorganische und Analytische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/429317549?language=en
• 关键词: Synthesis; characterization; reactivity; studies; ozonido

Main goal of the project is the synthesis and characterization of transition metal (iron, nickel, cobalt and copper) ozonido complexes and furthermore corresponding oxido complexes. Their reactivity in regard to oxidation of organic substrates will be investigated. Stabilization of ozonido complexes should be accomplished to allow their crystallographic characterization. This could lead to a future application (in situ) in organic synthesis. A long term goal will be the immobilization of either oxido or ozonido complexes (e. g. in silica) to make them useful for practical applications in catalytic oxidation reactions.

该项目的主要目标是合成和表征过渡金属（铁，镍，钴和铜）臭氧配合物以及相应的氧化配合物。将研究它们在有机底物氧化方面的反应性。应实现臭氧络合物的稳定化以允许其晶体学表征。这可能会导致未来的应用（原位）在有机合成。一个长期的目标将是固定氧化或臭氧复合物（如。G.在二氧化硅中）以使它们可用于催化氧化反应中的实际应用。