Formation, reactivity tuning and kinetic investigations of iron "dioxygen" intermediate complexes and derivatives in multiphase flow reactions

多相流反应中铁“双氧”中间配合物和衍生物的形成、反应性调节和动力学研究

• 批准号: 256663228
• 负责人: Professor Dr. Siegfried Schindler
• 金额: --
• 依托单位: Institut für Anorganische und Analytische Chemie
• 依托单位国家: 德国
• 项目类别: Priority Programmes
• 财政年份: 2014
• 资助国家: 德国
• 起止时间: 2013-12-31 至 2020-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/256663228?language=en
• 关键词: Formation; reactivity; tuning; kinetic; investigations

Selective oxidations of organic substrates especially hydrocarbons using air as an oxidant are important reactions in homogeneous catalysis. While regular kinetic investigations in the lab (e. g. using stopped-flow measurements) can provide solid basic information regarding the mechanism of such reactions, the reactivity can be quite different in an industrial process setup. The major goal of this research project is the development of iron catalysts for selective catalytic oxidation reactions. The final goal then would be to use these compounds on an industrial scale. Especially in co-operation with the other research groups of the SPP a reactivity tuning should be achieved for selectivity of oxidation products.

以空气为氧化剂的有机物特别是烃类的选择性氧化是均相催化中的重要反应。虽然在实验室中进行常规动力学研究（e。G.使用停流测量）可以提供关于这种反应机理的可靠的基本信息，但是在工业过程设置中反应性可能非常不同。本研究计画的主要目标是开发用于选择性催化氧化反应的铁催化剂。最终的目标是在工业规模上使用这些化合物。特别是在与SPP的其他研究小组的合作中，应实现对氧化产物的选择性的反应性调整。