Formation, reactivity tuning and kinetic investigations of iron "dioxygen" intermediate complexes and derivatives in multiphase flow reactions

在均相催化中，以空气为氧化剂的有机底物特别是碳氢化合物的选择性氧化是重要的反应。虽然在实验室中进行常规的动力学研究（例如使用停流测量）可以提供有关此类反应机理的可靠基本信息，但在工业过程设置中，反应性可能会大不相同。本研究项目的主要目标是开发用于选择性催化氧化反应的铁催化剂。最终目标是在工业规模上使用这些化合物。特别是在与SPP其他研究小组的合作下，应实现氧化产物选择性的反应性调整。

Selective oxidations of organic substrates especially hydrocarbons using air as an oxidant are important reactions in homogeneous catalysis. While regular kinetic investigations in the lab (e. g. using stopped-flow measurements) can provide solid basic information regarding the mechanism of such reactions, the reactivity can be quite different in an industrial process setup. The major goal of this research project is the development of iron catalysts for selective catalytic oxidation reactions. The final goal then would be to use these compounds on an industrial scale. Especially in co-operation with the other research groups of the SPP a reactivity tuning should be achieved for selectivity of oxidation products.