非線形光学材料の開発を目的とする電荷移動型共役化合物に関する研究

以开发非线性光学材料为目的的电荷转移型共轭化合物研究

• 批准号: 05640650
• 负责人: 樋口 弘行
• 金额: $ 1.28万
• 依托单位: University of Toyama
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (C)
• 财政年份: 1993
• 资助国家: 日本
• 起止时间: 1993 至 无数据
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-05640650/
• 关键词: 非線形光学効果; 電荷移動; 共役化合物; 第三次高調波発生; 分子超分極率

本研究では,電荷移動型共役化合物の非線形光学効果に関する研究の一環として,1,2のほか関連する大環状共役化合物の合成,構造解析およびそれらの電子的および光学的性質の検討を行なった.1および2の合成は研究計画・方法に基づき,1についてはn=1,2,4, 2についてはX=NO_2,H,Me,OMeの各誘導体の合成に成功した.紫外・可視吸収スペクトルにおいて,顕著な溶媒効果を示す電荷移動型吸収帯が観察されることから,1および2は,予想通り,分極構造の高い寄与を有する共役化合物であることがわかった.1の非線形光学効果に関する情報を得るために,参照化合物3,4とともに第三次高調波発生法(THG)により,3次の分子超分極率<γ>を測定した.その結果,i)共役末端にシアノ基の導入,ii)チオフェン環の数,iii)π-共役平面性の増大,とともに3次の非線形光学効果が高まることを明らかにすることができた。現在,ポルフィリン誘導体2について光学的性質を測定中であり,非線形光学効果と分極構造との相関性について検討する予定である。

The purpose of this study is to study the non-shape optical properties of charge-transfer co-operation compounds. in this study, the results of the study of non-shaped optical compounds in charge-transfer co-operation, the synthesis of large-scale environmental co-service compounds, the synthesis of large-scale environmental co-service compounds, the synthesis of charge-transfer co-active compounds, the synthesis of non-shaped optical compounds, the synthesis of non-conformal optical compounds, the synthesis of large-scale ambient co-operating compounds, the synthesis of large-scale ambient co-operating compounds, the synthesis of charge-moving co-operating compounds, the synthesis of non-shaped optical compounds, the synthesis of non-shaped optical compounds, the synthesis of The synthesis of each body of Me,OMe was successful. Ultraviolet (UV) can be used to observe the effect of the solvent on the temperature, and the effect of the solvent shows that the charge transfer type absorber detects the temperature of the vehicle, and you want to know if you want to know it, and you want to know how much you want to use it. In this way, you can use ultraviolet light to monitor the effect of ultraviolet light on the performance of common compounds with metal ions. Refer to the third high-wave biological method (THG) of compound 3pyrine, the molecular hyper-fractionation rate of compound 3pyrine & lt γ-gt; is used to determine the temperature. The results of the experiment are as follows: I) the number of end-to-end applications, ii) the number of environments, iii) the planarity of π-co-operation is high, and the results show that the non-linear optical performance is high for three times. At present, in the measurement of optical properties, non-shaped optics are very important in the determination of optical properties.

项目成果

Hiroyuki Higuchi: "Synthesis of Methano-bridged Tetradehydro[36]annulene" J.Chem.Soc.,Perkin Trans.I. 983-986 (1993)

Hiroyuki Higuchi：“甲醇桥联的四氢[36]轮烯的合成”J.Chem.Soc.，Perkin Trans.I。

Hiroyuki Higuchi: "Annelated Dehydroannulenes with Azulene Ring.The Synthesis of Bisdehydro[14]- and -[16]annuleno[a]azulene." Tetrahedron Lett.35(印刷中). (1994)

Hiroyuki Higuchi：“带有甘菊环的脱水环烯。双脱氢[14]-和-[16]环烯[a]甘菊烯的合成。”35（出版中）。

Gaku Yamamoto: "Unusual Formation of a Methano-Bridged Didehydro[20]annulenedione.A Highly Diatropic,Dicationic 18π-Electron Species in D_2SO_4." J.Chem.Soc.,Chem.Commun.698-699 (1993)

Gaku Yamamoto：“甲醇桥联的二脱氢[20]环烯二酮的异常形成。D_2SO_4 中的高度双变性、双阳离子 18π-电子物种。J.Chem.Soc.，Chem.Commun.698-699 (1993)

Hiroyuki Higuchi: "Synthesis of Methano-Bridged Tetradehydroaza[22]annulene and the Related Compounds" J.Chem.Soc.,Perkin Trans.I. 975-982 (1993)

Hiroyuki Higuchi：“甲醇桥四氢氮杂[22]轮烯和相关化合物的合成”J.Chem.Soc.，Perkin Trans.I.

Hiroyuki Higuchi: "Synthesis of Dibenzotrisdehydro[16]annulene-1,4-dione and the Related Compounds." Bull.Chem.Soc.Jpn.66. 2323-2329 (1993)

Hiroyuki Higuchi：“二苯并三脱氢[16]轮烯-1,4-二酮及相关化合物的合成”。