Identification, Synthesis, and Application of Novel Enantiomerically Pure Titanocenes – Cyclic Voltammetry, Electrolysis, and Supramolecular Chemistry in Concert

新型对映体纯二茂钛的鉴定、合成和应用——循环伏安法、电解和超分子化学的协同作用

• 批准号: 432405389
• 负责人: Professor Dr. Andreas Gansäuer
• 金额: --
• 依托单位: Kekulé-Institut für Organische Chemie und Biochemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/432405389?language=en
• 关键词: Identification; Synthesis; Application; Novel; Enantiomerically

We will demonstrate that the CV-screening of supramolecular halide receptors with titanocene complexes is an attractive predictive method for novel electrochemical or chemical syntheses of enantiomerically pure titanocene(III) complexes. We will probe the performance of these complexes in a number of catalytic pertinent reactions. The method should be of interest for other complexes, too. Therefore, it will be expanded to other titanium(III) catalysts. Investigations with other low-valent metal complexes are long-term goals to be pursued after the realization of this project.

我们将证明，超分子卤化物受体与茂钛配合物的循环伏安筛选是一种新的电化学或化学合成对映体纯钛茂(III)配合物的有吸引力的预测方法。我们将探索这些配合物在一些催化相关反应中的性能。这种方法对其他络合物也应该是有意义的。因此，它将扩展到其他钛(III)催化剂。对其他低价金属络合物的研究是该项目实现后要追求的长期目标。