All-carbon molecules in metal complexes - novel materials and intermediates

金属配合物中的全碳分子——新型材料和中间体

• 批准号: DP0557815
• 负责人: Prof Michael Bruce
• 金额: $ 39.22万
• 依托单位: The University of Adelaide
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2005
• 资助国家: 澳大利亚
• 起止时间: 2005-01-01 至 2009-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0557815
• 关键词: carbon; molecules; metal; complexes; novel

An important requirement for the future is new materials with unusual properties that can be controlled. The need for ever smaller electronic devices requires knowledge about appropriate properties (particularly electronic) of molecules designed to model devices such as wires, switches, etc. This work seeks to design, measure and evaluate such molecules, which are based on chains of carbon atoms linking metal centres which can gain or lose electrons readily. As the electronic structure changes, so do the physical (photo, solid-state) and chemical properties (reactivity). Improved understanding of these features will benefit development of advanced technology and new materials.

未来的一个重要需求是具有可控制的不寻常特性的新材料。 需要越来越小的电子设备需要知识的适当属性（特别是电子）的分子设计的模型设备，如电线，开关等，这项工作旨在设计，测量和评估这样的分子，这是基于碳原子链连接金属中心，可以容易地获得或失去电子。 随着电子结构的变化，物理（光，固态）和化学性质（反应性）也会发生变化。 对这些特性的深入了解将有助于先进技术和新材料的开发。