The development and application of highly efficient reagent having dual main group elements in a molecule

在这项研究中，我成功地利用一个分子中含有两个硅原子的试剂进行还原烷基化反应，如下所示：在二硅氧烷和Ru簇合物的催化下，富电子芳环与酯的还原烷基化反应。在类似的条件下，完成了对甲苯磺酰胺的还原烷基化反应。在研究过程中，我意外地在硅烷和Ru簇合物催化条件下得到了乙烯基醚(CH2=CHO)的重排产物(RCH2CHO)。

In this research, I successfully obtained the reactions of esters by using reagents havingdual silicon atoms in one molecule for reductive alkylations shown belowReductive alkylations of electron-rich aromatic rings with ester as an alkylatingreagent in the presence of disiloxane and ruthenium-cluster catalyst.Under the similar conditions of 1), reductive alkylations of tosylamides were accomplished.During the course of the research, I unexpectedly obtained rearrangement products(RCH2CHO) of vinyl ethers(CH2=CHOR) under silane and ruthenium-cluster catalystconditions.