The development and application of highly efficient reagent having dual main group elements in a molecule

在本研究中，我成功地获得了酯的反应，使用在一个分子中具有双硅原子的试剂进行还原烷基化反应如下：在二硅氧烷和铑簇催化剂存在下，以酯为烷基化剂，富电子芳环的还原烷基化。在类似于1）的条件下，完成了对甲苯磺酰胺的还原烷基化反应。在研究过程中，我意外地得到了乙烯基醚（CH_2 =CHOR）在硅烷和铼簇催化剂条件下的重排产物（RCH_2CHO）。

In this research, I successfully obtained the reactions of esters by using reagents havingdual silicon atoms in one molecule for reductive alkylations shown belowReductive alkylations of electron-rich aromatic rings with ester as an alkylatingreagent in the presence of disiloxane and ruthenium-cluster catalyst.Under the similar conditions of 1), reductive alkylations of tosylamides were accomplished.During the course of the research, I unexpectedly obtained rearrangement products(RCH2CHO) of vinyl ethers(CH2=CHOR) under silane and ruthenium-cluster catalystconditions.