Preparation of Hybrids Composed of Hyperbranched Polymers

超支化聚合物杂化物的制备

基本信息

批准号：
11450353
负责人：
KAKIMOTO Masa-aki
金额：
$ 9.15万
依托单位：
Tokyo Institute of Technology
依托单位国家：
日本
项目类别：
Grant-in-Aid for Scientific Research (B)
财政年份：
1999
资助国家：
日本
起止时间：
1999 至 2001
项目状态：
已结题

项目摘要

In this research, various structural Dendoriticc polymers which had been able to become the matrix polymer first of all in the future were synthesized. They are aroma family Poriamidodendorimar, the hyper branch polymer, the aroma family polyimide hyper branch polymer, and Porishirokisanhaiparbrantiporimar, etc. The acrylyl group was introduced into the end of this especially easy aroma family polyimide hyper branch polymer to synthesize, the copolymerization of those single polymerizations or the acrylate ester coexistence was done, and it succeeded in making of the complex which assumed the Dendoriticc polymer to be Kazunari amount. The complex's which had obtained it giving a tough film cpmpared with original Dendoriticcporiamid became clear. Next, the hyper branch polyamide silica complex was made by an anhydrous Zolugel reaction of Tetoraetokishishiran which used the formic acid under the hyper branch polyamide existence as a solvent and reactive Tamezai. It was possible to do, an … More d surprisingly, it became, and Sout succeeded in making a transparent film in the appearance of organic polymer and inorganic silica in this faction. This material is sure to be going to say the tough glass, and come not to crack easily because of the usual glass if it sees from the glass side. Moreover, the usage as the adhesive of the glass is thought because a uniform solution at the former stage of the Zolugel reaction. To introduce silicon into the hyper branch polymer side, the hyper branch polymer of the Porishirokisan frame was synthesized. When the amino group was introduced into the end radical of the obtained hyper branch polymer, it made having the character of one molecule micelle as it became meltable and a main chain took the coloring matter of hydrophobe into the hydrochloric acid water though it was Porishirokisan of hydrophobe clear. Moreover, radical Cyril was generated by an optical irradiation when the end was Fenilshiril radical, and constructing the hyper branch polymer happened. Less

在这项研究中，合成了各种能够成为基质聚合物的各种结构性树枝状聚合物。 They are aroma family Poriamide Dendorimar, the hyper branch polymer, the aroma family polyimide hyper branch polymer, and Porishirokisanhaiparbrantiporimar, etc. The acrylyl group was introduced into the end of this especially easy aroma family polyimide hyperbranch polymer to synthesize, the copolymerization of those single polymerizations or the acrylic ester coexistence was done, and it succeeded在制造假设树齿聚合物为kazunari量的复合物中。获得了它的综合大楼，这使一部艰难的电影用原始的dendoriticcporiamid比较清楚了。接下来，超级分支多酰胺二氧化硅复合物是由四埃氏菌的无水Zolugel反应制成的，该反应在超级分支聚酰胺下使用的形式酸用作溶剂和反应性tamezai。在这一事实中，这是有可能做到的，更令人惊讶的是，它变成了它，Sout成功地制作了有机聚合物和无机二氧化硅的透明电影。这种材料肯定会说坚韧的玻璃，如果从玻璃一侧看到通常的玻璃，就不会轻易破裂。此外，考虑到玻璃的粘合剂的用法是因为在Zolugel反应的前阶段的均匀解决方案。为了将硅引入超分支聚合物侧，合成了孔叶鼠框架的高分支聚合物。当将氨基组引入所获得的高分支聚合物的末端时，它具有一个分子胶束的特征，因为它变得可融化，并且一条主链将疏水物的着色物吸入了盐酸水中，尽管它是疏水物的孔子。此外，当末端是fenilshiril自由基时，从光照射产生了自由基西里尔，并发生了构造超支分支聚合物的发生。较少的