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Preparation of Hybrids Composed of Hyperbranched Pclymers

超支化聚合物杂化物的制备

基本信息

批准号：
11555247
负责人：
KAKIMOTO Masa-aki
金额：
$ 6.14万
依托单位：
Tokyo Institute of Technology
依托单位国家：
日本
项目类别：
Grant-in-Aid for Scientific Research (B)
财政年份：
1999
资助国家：
日本
起止时间：
1999 至 2001
项目状态：
已结题

项目摘要

It is known do the hydrolysis of Asetarl under an acid condition. The attempt to induce the frame change of Asetarl to a dissolubility difference under the existence of the Hicasan generation medicine has been done by using such a decomposition reaction in Fotoreges and the field. A main chain was made to cut it in this research when the Asetarl frame was introduced into a main chain of the polyimide, and light was hit. That is, it functions as resist of the Poge type. In addition, because the scrap after this resin is used also decomposes the acid, it becomes an environment-friendly material. First of all, the Geamin body which was the polyimide monomer including the Asetarl structure was synthesized. Crystalline of this one was accompanied low by the raft of trouble though Geamin which had the Gefenilbenzal radical had been synthesized as a new structure above. On the other hand, it has been understood not to obtain the high polymerization body by this method though the possibility o … More f the reaction of Bifenorl which has the Imid frame and Benzalcrorid was examined as a method of not passing Geamin easily. The generated acid was a sulfonic acid, and it was difficult to say at all a strong acid though the one * here is absorption in the long wave length area was synthesized and had been used as Hicasan generation medicine which bore phototonus directly. Then, the Hicasan generation medicine where the boron of making to Ftsu acid which was the strong acid was newly generated was synthesized. It left Benzaldehid which introduced the Torifloro methyl radical into the Holt title as new monomer, p-Nitorofenilasetarl structure was constructed, it reduced to the Geamino body, and it synthesized it. The polyamide acid was obtained because of the reaction of Geamin and two various tetra carboxylic acid anhydrides which had new Asetarl, and, in addition, the polyimide film including the Asetarl structure was obtained. Because it obtains and the film dissolves to the org.solvent, the film can be made directly by the polyimide. When Patterning was done by using g line for the obtained film, an excellent pattern was able to be obtained. The amid acid anhydride monomer was newly synthesized by the reaction of Geamin which had Asetarl and Tori advantage acid Crorid, and it was made to react with various Geamin, and next, the polyamide acid was obtained, and, in addition, the polyimide film including the Asetarl structure was obtained. As for the obtained polyimide, excellent heatproof was able to be possessed, and make the org.solvent the consisting material handily in addition by the Samac Patterning because it is meltable. Less

已知在酸的条件下进行石笋的水解。利用这种分解反应在Fotoreges和野外进行，试图在Hicasan代药存在的情况下，诱导Asetarl的框架变化为溶出度差异。本研究在聚酰亚胺的主链中引入Asetarl框架，并对其进行光冲击，制成了一个主链来切割它。也就是说，它起着Poge型抗蚀剂的作用。此外，由于这种树脂使用后的废料也会分解酸，因此成为一种环保材料。首先合成了具有Asetarl结构的聚酰亚胺单体Geamin体；虽然合成了具有Gefenilbenzal自由基的Geamin作为上述新结构，但该化合物的结晶却伴随着大量的麻烦。另一方面，通过对具有酰亚胺骨架的双酚与苯扎氯胺反应的可能性的研究，也了解了这种方法不能得到高聚合体。生成的酸为磺酸，虽然合成了长波区吸收的1 *，但很难说是强酸，并被用作直接产生光张力的Hicasan代药。然后，合成了以新生成的强酸制硼酸为原料的Hicasan代药。左苯扎尔德（Benzaldehid）将Torifloro甲基自由基引入Holt标题作为新单体，构建了对硝基苯基（nitorofenilasetaral）结构，还原为基氨基体，并进行了合成。以两种不同的四羧酸酸酐为原料，通过反应得到了具有新Asetarl结构的聚酰亚胺酸，并得到了具有Asetarl结构的聚酰亚胺膜。因为它得到并且薄膜溶解到组织中。溶剂，薄膜可直接由聚酰亚胺制成。用g线对所得到的薄膜进行图案化处理，可以得到很好的图案化效果。以具有Asetarl和Tori优势酸基团的Geamin为原料，合成了一种新型的amid酸酐单体，并与多种Geamin反应，制得聚酰胺酸，得到具有Asetarl结构的聚酰亚胺薄膜。所制得的聚酰亚胺具有良好的耐热性，并可制成有机材料。由于其可熔融性，因此很容易地通过Samac图版将组成材料溶化。少