Preparation of Hybrids Composed of Hyperbranched Pclymers

已知Asetarl在酸性条件下发生水解。通过在Fotoreges和野外的这种分解反应，尝试在Hicasan世代药物存在的情况下，将Asetarl的框架变化诱导为溶解度差。在本研究中，将Asetarl骨架引入到聚酰亚胺的主链中，并对其进行光照，从而制作了主链进行切割。也就是说，它起到了Poge类型的抗蚀剂的作用。此外，由于该树脂使用后的废料也分解了酸，因此成为一种环保材料。首先，合成了含有Asetarl结构的聚酰亚胺单体Geamin本体。这一化合物的结晶伴随着大量的麻烦，尽管上面已经合成了一种新的结构，即具有基苯基苯甲醛的Geamin。另一方面，已经理解，尽管…的可能性不能通过该方法获得高聚合体此外，还考察了具有IMID骨架的联苯诺醇的反应，认为这是一种不容易通过Geamin的方法。生成的酸是一种磺酸，虽然这里的是长波吸收，但很难说出是强酸，并已被用作直接携带光敏剂的平山世代药物。在此基础上，合成了将制得的强酸Ftsu酸中的硼重新生成的Hicasan代用药物。它离开了在Holt标题中引入Torifloro甲基自由基的苯甲醛作为新的单体，构建了对硝基苯乙酸酯结构，将其还原为Ge氨基体，并合成了它。通过乙二胺与两种不同类型的含有新细辛醇的四元酸酐反应，得到聚酰胺酸，并得到了含有细辛醇结构的聚酰亚胺薄膜。由于它的存在，薄膜溶解到有机溶剂中，所以薄膜可以直接由聚酰亚胺制成。当使用g线对所获得的薄膜进行图案化时，能够获得良好的图案化。将含有Asetarl和Tori Advantage ACID的Geamin与不同的Geamin反应，新合成了酰胺酸酐单体，然后与不同的Geamin反应，得到聚酰胺酸，并得到了含有Asetarl结构的聚酰亚胺薄膜。对于得到的聚酰亚胺，由于其具有良好的耐热性，而且由于它是可熔化的，所以通过SAMAC图案化可以方便地将有机溶剂作为组成材料。较少

It is known do the hydrolysis of Asetarl under an acid condition. The attempt to induce the frame change of Asetarl to a dissolubility difference under the existence of the Hicasan generation medicine has been done by using such a decomposition reaction in Fotoreges and the field. A main chain was made to cut it in this research when the Asetarl frame was introduced into a main chain of the polyimide, and light was hit. That is, it functions as resist of the Poge type. In addition, because the scrap after this resin is used also decomposes the acid, it becomes an environment-friendly material. First of all, the Geamin body which was the polyimide monomer including the Asetarl structure was synthesized. Crystalline of this one was accompanied low by the raft of trouble though Geamin which had the Gefenilbenzal radical had been synthesized as a new structure above. On the other hand, it has been understood not to obtain the high polymerization body by this method though the possibility o … More f the reaction of Bifenorl which has the Imid frame and Benzalcrorid was examined as a method of not passing Geamin easily. The generated acid was a sulfonic acid, and it was difficult to say at all a strong acid though the one * here is absorption in the long wave length area was synthesized and had been used as Hicasan generation medicine which bore phototonus directly. Then, the Hicasan generation medicine where the boron of making to Ftsu acid which was the strong acid was newly generated was synthesized. It left Benzaldehid which introduced the Torifloro methyl radical into the Holt title as new monomer, p-Nitorofenilasetarl structure was constructed, it reduced to the Geamino body, and it synthesized it. The polyamide acid was obtained because of the reaction of Geamin and two various tetra carboxylic acid anhydrides which had new Asetarl, and, in addition, the polyimide film including the Asetarl structure was obtained. Because it obtains and the film dissolves to the org.solvent, the film can be made directly by the polyimide. When Patterning was done by using g line for the obtained film, an excellent pattern was able to be obtained. The amid acid anhydride monomer was newly synthesized by the reaction of Geamin which had Asetarl and Tori advantage acid Crorid, and it was made to react with various Geamin, and next, the polyamide acid was obtained, and, in addition, the polyimide film including the Asetarl structure was obtained. As for the obtained polyimide, excellent heatproof was able to be possessed, and make the org.solvent the consisting material handily in addition by the Samac Patterning because it is meltable. Less