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Preparation of Hybrids Composed of Hyperbranched Pclymers

Preparation of Hybrids Composed of Hyperbranched Pclymers
超支化聚合物杂化物的制备
批准号:
11555247
负责人:
KAKIMOTO Masa-aki
金额:
$6.14万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (B)
财政年份:
1999
资助国家:
日本
项目状态:
已结题
起止时间:
1999 至 2001

项目摘要

项目成果

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中文摘要
翻译
已知阿斯塔尔在酸性条件下水解。通过使用Fotoreges和该领域中的这种分解反应,在Hicasan代药物的存在下,已经完成了将Asetar的结构变化诱导为溶解度差异的尝试。在聚酰亚胺主链上引入Asetarl框架,使其主链断裂,产生光照射。也就是说,其用作Poge类型的抗蚀剂。此外,由于这种树脂使用后的废料也会分解酸,因此成为环保材料。首先,合成了具有Asetarl结构的聚酰亚胺单体Geamin体。虽然已经合成了具有Gefenilbenzal基团的Geamin作为上述新结构,但这种晶体伴随着大量的麻烦。另一方面,已经理解的是,尽管存在聚合的可能性,但通过该方法不能获得高聚合体。 关于我们 对具有亚胺骨架的联苯双酯与苄叉丙酮的反应进行了研究,作为一种不容易通过Geamin的方法。所生成的酸是磺酸,虽然在长波长区有吸收,但很难说是强酸,已被合成并用作直接产生光紧张的Hicasan代药。然后,合成了新生成的对强酸Ftsu酸进行硼化的Hicasan代药物。在Holt标题中引入了Torifloro甲基的苯甲醛作为新的单体,构建了对硝基苯胺的结构,将其还原为Geamino体,合成了Geamino体,Geamin与两种具有新的Asetar结构的四羧酸酐反应得到聚酰胺酸,并得到了含有Asetar结构的聚酰亚胺薄膜。由于它能溶解于有机溶剂中,因此可直接用聚酰亚胺制膜。当通过使用g线对所获得的膜进行图案化时,能够获得优异的图案。通过具有Asetar结构的Geamin与具有Tori优势酸Crorid的Geamin反应,合成了酰胺酸酐单体,并将其与各种Geamin反应,得到聚酰胺酸,进而得到具有Asetar结构的聚酰亚胺薄膜。对于所得聚酰亚胺,能够具有优异的耐热性,并且由于其是可熔融的,另外通过Samac图案化容易地使有机溶剂成为组成材料。少
英文摘要
It is known do the hydrolysis of Asetarl under an acid condition. The attempt to induce the frame change of Asetarl to a dissolubility difference under the existence of the Hicasan generation medicine has been done by using such a decomposition reaction in Fotoreges and the field. A main chain was made to cut it in this research when the Asetarl frame was introduced into a main chain of the polyimide, and light was hit. That is, it functions as resist of the Poge type. In addition, because the scrap after this resin is used also decomposes the acid, it becomes an environment-friendly material. First of all, the Geamin body which was the polyimide monomer including the Asetarl structure was synthesized. Crystalline of this one was accompanied low by the raft of trouble though Geamin which had the Gefenilbenzal radical had been synthesized as a new structure above. On the other hand, it has been understood not to obtain the high polymerization body by this method though the possibility o … More f the reaction of Bifenorl which has the Imid frame and Benzalcrorid was examined as a method of not passing Geamin easily. The generated acid was a sulfonic acid, and it was difficult to say at all a strong acid though the one * here is absorption in the long wave length area was synthesized and had been used as Hicasan generation medicine which bore phototonus directly. Then, the Hicasan generation medicine where the boron of making to Ftsu acid which was the strong acid was newly generated was synthesized. It left Benzaldehid which introduced the Torifloro methyl radical into the Holt title as new monomer, p-Nitorofenilasetarl structure was constructed, it reduced to the Geamino body, and it synthesized it. The polyamide acid was obtained because of the reaction of Geamin and two various tetra carboxylic acid anhydrides which had new Asetarl, and, in addition, the polyimide film including the Asetarl structure was obtained. Because it obtains and the film dissolves to the org.solvent, the film can be made directly by the polyimide. When Patterning was done by using g line for the obtained film, an excellent pattern was able to be obtained. The amid acid anhydride monomer was newly synthesized by the reaction of Geamin which had Asetarl and Tori advantage acid Crorid, and it was made to react with various Geamin, and next, the polyamide acid was obtained, and, in addition, the polyimide film including the Asetarl structure was obtained. As for the obtained polyimide, excellent heatproof was able to be possessed, and make the org.solvent the consisting material handily in addition by the Samac Patterning because it is meltable. Less
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会议论文
寺境光俊,柿本雅明: "分岐ポリマーのテクノロジー"アイピーシー. 212 (2000)
Mitsutoshi Terasaka、Masaaki Kakimoto:“支化聚合物技术”IPC 212 (2000)。
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通讯作者:
S.Akimoto et al.: "A Novel Main Chain Creavable Photosensitive Polyimide; Polyimide Containing Acetal Structure with Photoacid Generator"J.Photopolym.Sci.Technol.. 12(2). 245-248 (1999)
S.Akimoto 等人:“新型主链可断裂光敏聚酰亚胺;含缩醛结构的聚酰亚胺,具有光致产酸剂”J.Photopolym.Sci.Technol.. 12(2)。
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作者: []
通讯作者:
寺境光俊,柿本雅明: "デンドリマーの科学と機能"アイピーシー. 320 (2000)
Mitsutoshi Terasaka、Masaaki Kakimoto:“树枝状聚合物的科学和功能”IPC 320 (2000)。
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通讯作者:
Preparation of Hybrids Composed of Hyperbranched Polymers
  • 批准号:
    11450353
  • 项目类别:
    Grant-in-Aid for Scientific Research (B)
  • 资助金额:
    $9.15万
  • 财政年份:
    1999
  • 负责人:
    KAKIMOTO Masa-aki
  • 依托单位:
Synthesis of Poly (thioether) s by Nucleophilic Substitution of Chromium-Arene Complex
  • 批准号:
    08651046
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
  • 资助金额:
    $1.41万
  • 财政年份:
    1996
  • 负责人:
    KAKIMOTO Masa-aki
  • 依托单位:
Preparation of Plasma Polymerized Films in D.C.Glow
  • 批准号:
    06555284
  • 项目类别:
    Grant-in-Aid for Developmental Scientific Research (B)
  • 资助金额:
    $2.43万
  • 财政年份:
    1994
  • 负责人:
    KAKIMOTO Masa-aki
  • 依托单位:
Application of Polyimide Langmuir-Blodgett Films to Selective Gas Permeation
  • 批准号:
    63850180
  • 项目类别:
    Grant-in-Aid for Developmental Scientific Research
  • 资助金额:
    $4.42万
  • 财政年份:
    1988
  • 负责人:
    KAKIMOTO Masa-aki
  • 依托单位:
国内基金
海外基金
纤维二糖酶的固定化及纤维素水解辅助技术
  • 批准号:
    30471361
  • 项目类别:
    面上项目
  • 资助金额:
    18.0万元
  • 批准年份:
    2004
  • 负责人:
    勇强
  • 依托单位: