Preparation of Hybrids Composed of Hyperbranched Pclymers
Preparation of Hybrids Composed of Hyperbranched Pclymers
批准号:
11555247
负责人:
KAKIMOTO Masa-aki
金额:
$6.14万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (B)
财政年份:
1999
资助国家:
日本
项目状态:
已结题
起止时间:
1999 至 2001
中文摘要
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英文摘要
It is known do the hydrolysis of Asetarl under an acid condition. The attempt to induce the frame change of Asetarl to a dissolubility difference under the existence of the Hicasan generation medicine has been done by using such a decomposition reaction in Fotoreges and the field. A main chain was made to cut it in this research when the Asetarl frame was introduced into a main chain of the polyimide, and light was hit. That is, it functions as resist of the Poge type. In addition, because the scrap after this resin is used also decomposes the acid, it becomes an environment-friendly material. First of all, the Geamin body which was the polyimide monomer including the Asetarl structure was synthesized. Crystalline of this one was accompanied low by the raft of trouble though Geamin which had the Gefenilbenzal radical had been synthesized as a new structure above. On the other hand, it has been understood not to obtain the high polymerization body by this method though the possibility o … More f the reaction of Bifenorl which has the Imid frame and Benzalcrorid was examined as a method of not passing Geamin easily. The generated acid was a sulfonic acid, and it was difficult to say at all a strong acid though the one * here is absorption in the long wave length area was synthesized and had been used as Hicasan generation medicine which bore phototonus directly. Then, the Hicasan generation medicine where the boron of making to Ftsu acid which was the strong acid was newly generated was synthesized. It left Benzaldehid which introduced the Torifloro methyl radical into the Holt title as new monomer, p-Nitorofenilasetarl structure was constructed, it reduced to the Geamino body, and it synthesized it. The polyamide acid was obtained because of the reaction of Geamin and two various tetra carboxylic acid anhydrides which had new Asetarl, and, in addition, the polyimide film including the Asetarl structure was obtained. Because it obtains and the film dissolves to the org.solvent, the film can be made directly by the polyimide. When Patterning was done by using g line for the obtained film, an excellent pattern was able to be obtained. The amid acid anhydride monomer was newly synthesized by the reaction of Geamin which had Asetarl and Tori advantage acid Crorid, and it was made to react with various Geamin, and next, the polyamide acid was obtained, and, in addition, the polyimide film including the Asetarl structure was obtained. As for the obtained polyimide, excellent heatproof was able to be possessed, and make the org.solvent the consisting material handily in addition by the Samac Patterning because it is meltable. Less
期刊论文(5)
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科研奖励(0)
会议论文
寺境光俊,柿本雅明: "分岐ポリマーのテクノロジー"アイピーシー. 212 (2000)
Mitsutoshi Terasaka、Masaaki Kakimoto:“支化聚合物技术”IPC 212 (2000)。
DOI:
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发表时间:
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影响因子:
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作者:
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通讯作者:
S.Akimoto et al.: "A Novel Main Chain Creavable Photosensitive Polyimide; Polyimide Containing Acetal Structure with Photoacid Generator"J.Photopolym.Sci.Technol.. 12(2). 245-248 (1999)
S.Akimoto 等人:“新型主链可断裂光敏聚酰亚胺;含缩醛结构的聚酰亚胺,具有光致产酸剂”J.Photopolym.Sci.Technol.. 12(2)。
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发表时间:
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作者:
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通讯作者:
寺境光俊,柿本雅明: "デンドリマーの科学と機能"アイピーシー. 320 (2000)
Mitsutoshi Terasaka、Masaaki Kakimoto:“树枝状聚合物的科学和功能”IPC 320 (2000)。
DOI:
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发表时间:
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影响因子:
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作者:
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通讯作者:
Preparation of Hybrids Composed of Hyperbranched Polymers
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批准号:11450353
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$9.15万
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财政年份:1999
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负责人:KAKIMOTO Masa-aki
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依托单位:
Synthesis of Poly (thioether) s by Nucleophilic Substitution of Chromium-Arene Complex
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批准号:08651046
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$1.41万
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财政年份:1996
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负责人:KAKIMOTO Masa-aki
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依托单位:
Preparation of Plasma Polymerized Films in D.C.Glow
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批准号:06555284
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项目类别:Grant-in-Aid for Developmental Scientific Research (B)
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资助金额:$2.43万
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财政年份:1994
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负责人:KAKIMOTO Masa-aki
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依托单位:
Application of Polyimide Langmuir-Blodgett Films to Selective Gas Permeation
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批准号:63850180
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项目类别:Grant-in-Aid for Developmental Scientific Research
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资助金额:$4.42万
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财政年份:1988
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负责人:KAKIMOTO Masa-aki
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依托单位:
国内基金
海外基金
纤维二糖酶的固定化及纤维素水解辅助技术
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批准号:30471361
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项目类别:面上项目
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资助金额:18.0万元
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批准年份:2004
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负责人:勇强
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依托单位: