Study on the crystal structure of deep sections of Antarctic ice cores

南极冰芯深部晶体结构研究

基本信息

  • 批准号:
    12440077
  • 负责人:
  • 金额:
    $ 9.09万
  • 依托单位:
  • 依托单位国家:
    日本
  • 项目类别:
    Grant-in-Aid for Scientific Research (B)
  • 财政年份:
    2000
  • 资助国家:
    日本
  • 起止时间:
    2000 至 2002
  • 项目状态:
    已结题

项目摘要

Characteristic features in Antarctic ice cores have been observed by Raman and incoherent inelastic neutron spectra, which have been attributed to proton ordering in ice structure. In this study, to elucidate the characteristic crystal structure of ice cores from Antarctica were investigated mainly by X-ray diffraction. The followings are the results in this research:(1) X-ray diffraction study of structure of ice crystalX-ray rocking curve measurements were conducted for deep sections of Vostok ice core and the dislocation density was determined from the width of the profiles. The dislocation density decreases from 10^<12>m^<-2> to 10^8 m^<-2>, as depth increases between 3200 and 3611 m. The dislocation density was lower in deepest sections because^the ice was formed by the refreezing of Vostok Lake water in a long period.(2) X-ray powder diffraction study of crystal structureThe observed profiles by X-ray powder diffraction did show sample or depth dependency. The (1121) reflection w … More hich is characteristic of ordered ice (ice XI) was scarcely observed in any samples. This is because the intensity of this reflection is expected to be very low and, therefore, strong X-ray source like synchrotron radiation is necessary in a further study. X-ray diffuse scattering measurements are also important in the further study.(3) Lattice constants determined by X-ray powder diffractionLattice constants of ice core samples were determined by Reidtveld analysis of X-ray powder diffraction profiles. The lattice constants of ice core samples are larger than that of laboratory ice and increase with the depth although they are expected to be smaller due to residual stress. The origin of this behavior should be investigated in a further study.(4) Raman Spectra of deformed iceTo reveal the origin of the reported characteristic spectra of Antarctic ice, Raman spectra for deformed ice were measured. However, no significant change was observed. Thus, the deformation of ice in the Antarctic ice sheet is not a possible reason for the characteristic spectra.(5) Formation process of clathrate hydrate and ice crystal structureMolecular dynamics simulations elucidated a new diffusion mechanism of gases in ice during clathrate hydrate formation from ice. We first found that in the diffusion process gas forms a characteristic intermediate structure breaking a hydrogen bond between a pair of water molecules. Less
南极冰芯的特征特征已被拉曼和非相干非弹性中子谱观测到,这些特征被归因于冰结构中的质子有序化。本研究主要利用X射线衍射技术研究南极冰芯的晶体结构特征。(1)冰晶结构的X射线衍射研究对东方号冰芯的深剖面进行了X射线摇摆曲线测量,并根据剖面宽度确定了位错密度。在3200 ~ 3611 m之间,随着深度的增加,位错密度从10 μ m ~ <12><-2>8 μ m减小到108 μ <-2>m。位错密度在最深处较低,这是由于沃斯托克湖水在较长时间内重新冻结形成的冰。(2)晶体结构的X射线粉末衍射研究通过X射线粉末衍射观察到的轮廓确实显示出样品或深度依赖性。(1121)反射W ...更多信息 这是有序冰(冰XI)的特征,在任何样品中几乎都没有观察到。这是因为这种反射的强度预计是非常低的,因此,在进一步的研究中,需要像同步辐射这样的强X射线源。X射线漫散射测量在进一步的研究中也是重要的。(3)用X射线粉末衍射法测定晶格常数用X射线粉末衍射的Reidtveld分析法测定了冰芯样品的晶格常数。冰芯样品的晶格常数大于实验室冰的晶格常数,并随着深度的增加而增加,尽管由于残余应力,它们预计会较小。这种行为的起源应在进一步的研究中进行调查。(4)变形冰的拉曼光谱为了揭示南极冰特征光谱的来源,测量了变形冰的拉曼光谱。然而,未观察到显著变化。因此,南极冰盖中冰的变形不是特征光谱的可能原因。(5)笼形水合物的形成过程及冰晶结构分子动力学模拟揭示了冰生成笼形水合物过程中气体在冰中的扩散机制。我们首先发现,在扩散过程中,气体形成了一个特征性的中间结构,打破了一对水分子之间的氢键。少

项目成果

期刊论文数量(42)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
H.Narita et al.: "Estimation of annual layer thickness from stratigraphical analysis of Dome Fuji deep ice core."Mem.Natl.Inst.Polar Res.Special Issue. 57. 38-45 (2003)
H.Narita 等人:“根据富士穹顶深冰芯的地层分析估算年层厚度。”Mem.Natl.Inst.Polar Res.Special Issue。
  • DOI:
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H.Narita et al.: "Estimation of annual layer thickness from stratigraphical analysis of Dome Fuji deep ice core"Mem. Natl. Inst. Polar Res. Special Issue. 57. 38-45 (2003)
H.Narita 等人:“根据富士穹顶深冰芯的地层分析估算年层厚度”Mem。
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    0
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T.Hondoh: "Nature and behavior of dislocation in ice"Physics of Ice Core Records, Edited by T.Hondoh Hokkaido University Press. 3-24 (2000)
T.Hondoh:“冰中位错的性质和行为”冰芯物理学记录,T.Hondoh 北海道大学出版社编辑。
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  • 影响因子:
    0
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T.Ikeda-Fukazawa et al.: "Variation in N2/O2 ratio of occluded air in Dome Fuji Antarctic ice"J. Geophys. Res.. 106,No.D16. 17,799-17,810 (2001)
T.Ikeda-Fukazawa 等:“南极富士穹顶冰中吸留空气的 N2/O2 比率的变化”J。
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    0
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T.Ikeda-Fukazawa et al.: "Variation in N_2/O_2 ratio of occluded air in Dome Fuji Antarctic ice"J.Geophys.Res.. 106, No.D16. 17799-17810 (2001)
T.Ikeda-Fukazawa等:“南极富士圆顶冰中吸留空气的N_2/O_2比率的变化”J.Geophys.Res.. 106,No.D16。
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HORI Akira其他文献

HORI Akira的其他文献

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{{ truncateString('HORI Akira', 18)}}的其他基金

Crystal structure study of ice from the Dome Fuji ice core by the X-ray diffraction reciprocal mapping measurements
通过 X 射线衍射倒数映射测量研究富士圆顶冰芯冰的晶体结构
  • 批准号:
    21560004
  • 财政年份:
    2009
  • 资助金额:
    $ 9.09万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
X-ray diffraction study of crystal structure and dislocation density of the Dome Fuji ice core
富士圆顶冰芯晶体结构和位错密度的 X 射线衍射研究
  • 批准号:
    19560002
  • 财政年份:
    2007
  • 资助金额:
    $ 9.09万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Archaeological Study on the Early Urban Civilization in Saudi Arabia
沙特阿拉伯早期城市文明的考古研究
  • 批准号:
    02041103
  • 财政年份:
    1990
  • 资助金额:
    $ 9.09万
  • 项目类别:
    Grant-in-Aid for international Scientific Research

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