Development of Sustainable Highly Selective Electrofluorination Using Electrocatalysis
Development of Sustainable Highly Selective Electrofluorination Using Electrocatalysis
批准号:
12555252
负责人:
FUCHIGAMI Toshio
金额:
$5.7万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (B)
财政年份:
2000
资助国家:
日本
项目状态:
已结题
起止时间:
2000 至 2002
中文摘要
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英文摘要
Selective fluorination of organic compounds is highly useful for development of medicines, agrochemicals, and functional materials. However, the fluorination methods have not been well developed. Therefore, we aimed the following projects through the new development of sustainable highly selective electrofluorination using electrocatalysis.1) Development of organic electrolytes for high performance rechargeable Li batteries2) Development of fluorinated biologically active compounds usinig electrocatalytic fluorodesulfurization3) Selective electrofluorination of organic compounds using diamonds electrodes4) Development of fluorinated ethers as flon substituentsWe have mostly achieved above projects and the results seem to be useful for future study on selective fluorination of various organic molecules.
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DAISUKE BABA: "Regio-and Diastereoselective Anodic Fluorination of Thiazolidines"Journal of Organic Chemistry. 66. 7020-7024 (2001)
DAISUKE BABA:“噻唑烷的区域和非对映选择性阳极氟化”有机化学杂志。
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Toshio Fuchigami: "Electrolytic Partial Fluorination of Organic Compounds.44. Anodic gem-Difluoro desulfurization Using Triarylamine Mediators"J. Electroanal. Chem.. 507. 30-33 (2001)
Toshio Fuchigami:“有机化合物的电解部分氟化。44。使用三芳胺介体的阳极二氟脱硫”J。
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Daisuke Baba: "Electrolytic Partial Fluorination of Organic Compound. 52. Regio- and Diastereoselective Anodic Fluorination of Thiazolidines"J. Org. Chem.. 66. 7020-7024 (2001)
Daisuke Baba:“有机化合物的电解部分氟化。52。噻唑烷的区域和非对映选择性阳极氟化”J。
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TOSHIO FUCHIGAMI: "ORGANIC ELECTROCHEMISTRY. 4TH EDITION"MARCEL DEKKER. 15 (2001)
Toshio Fuchigami:“有机电化学。第四版”MARCEL DEKKER。
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TOSHIO FUCHIGAMI: "Indirect Anodic Monofluorodesulfurization of β-Phenylsulfenyl β-lactams Using a Triarylamine Mediator"Synlett.. 1269-1271 (2001)
TOSHIO FUCHIGAMI:“使用三芳胺介体对 β-苯基硫基 β-内酰胺进行间接阳极单氟脱硫”Synlett.. 1269-1271 (2001)
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共 35 条
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