Organic Electrosynthesis in Ionic Liquids as Reaction Media

离子液体具有不挥发、易燃、高导电性和可回收性等特点，适合于环境友好的有机合成。另一方面，有机电合成是一个清洁的过程，但主要使用挥发性有机溶剂。用离子液体代替有机溶剂，可以发展环境友好的有机电极工艺。从这些观点出发，在聚HF盐离子液体中实现了各种有机化合物的阳极氧化、超声波作用下的高效阳极氧化、任务特异性离子液体的电催化氧化、聚合物的阳极氟化脱硫以及环化与聚合物合成的结合。在这个项目中开发的新方法似乎是非常有用的药物，农用化学品和功能材料的开发。

Ionic liquids are suitable for environmentally friendly organic synthesis since they are nonvolatile, inflammable, high conductive, and recyclable. On the other hand, organic electrosynthesis is a clean process, however, volatile organic solvents are mainly used. When ionic liquids are used instead of organic solvents, environmentally friendly organic electrode process would be developed. From these viewpoints, anodic fluorination of various organic compounds, highly efficient anodic fluorination under ultrasonication, electrocatalytic fluorination using task specific ionic liquid, anodic fluorodesulfurization of polymers, and cyclization together with polymer synthesis were achieved in poly HF salt ionic liquids. The new methodologies developed in this project seem to be highly useful for the development of pharmaceuticals, agrochemicals, and functional materials.