Organic Electrosynthesis in Ionic Liquids as Reaction Media

点击翻译按钮获取中文摘要

Ionic liquids are suitable for environmentally friendly organic synthesis since they are nonvolatile, inflammable, high conductive, and recyclable. On the other hand, organic electrosynthesis is a clean process, however, volatile organic solvents are mainly used. When ionic liquids are used instead of organic solvents, environmentally friendly organic electrode process would be developed. From these viewpoints, anodic fluorination of various organic compounds, highly efficient anodic fluorination under ultrasonication, electrocatalytic fluorination using task specific ionic liquid, anodic fluorodesulfurization of polymers, and cyclization together with polymer synthesis were achieved in poly HF salt ionic liquids. The new methodologies developed in this project seem to be highly useful for the development of pharmaceuticals, agrochemicals, and functional materials.