Development of New B2 Type Shape Memory Alloys end theirs Application for Multi-functional Devices.

新型B2型形状记忆合金的开发结束了其在多功能器件中的应用。

• 批准号: 13555181
• 负责人: KAINUMA Ryosuke
• 金额: $ 8.83万
• 依托单位: TOHOKU UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2001
• 资助国家: 日本
• 起止时间: 2001 至 2002
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-13555181/
• 关键词: Martensitic Transformation; Magnetic Transition; Ferromagnetic Shape Memory; Co-Ni-Al base; Sensor; Smart Materials; 規磁気変態; 強磁性形状記憶材料

Shape memory (SM) material which possesses double functions of thermo-sensor and actuator is one of the typical smart materials. Although the SM devices yield larger power and displacement than the ferroelectric one, they have a very serious problem in which the response for input signal is too slow, because the thermal conductivity in the SM devices is a rate determining process. Recently, ferromagnetic Shape memory (FSM) alloys that can be operated by magnetic field have been developed in the Ni-Mn-Ga system. In the present study, new type of FSMAs, Co-Ni-Al alloys with B2 bcc ordered structure were investigated.. The details of results obtained by the present work are as follows:(1) Transformation temperatures: Martensitic transformation temperature (Ms) and Curie temperature (Tc) were determined by DSC and VSM measurement. Some alloys have Ms and To in relatively high temperatures region over room temperature. This result means that the Co-Ni-Al alloys can be a candidate of the promising FSMA.(2) Crystal structure: The parent and martensits phases have B2 and Ll_0 structures, respectively. The c/a ration of the Ll_0, phase is 0.81.(3) Shape memory and mechanical properties: Coexistence with γ phase improves the ductility of alloys and a perfect SM can be obtained by a training treatment.(4) Magnetic properties: Magnetic anisotropies of austenite and martensite phases were determined using single crystals, and magnetostriction of about 0.3% was detected.(5) FSM wire, FSM wire with 0.5 to 1.0mmf could be produced by conventional techniques of rolling and drawing. The obtained wire showed a pseudoelastic behavior.

形状记忆材料是一种典型的智能材料，具有温度传感器和执行器的双重功能。虽然SM器件比铁电器件产生更大的功率和位移，但它们存在对输入信号的响应太慢的非常严重的问题，因为SM器件中的热导率是一个速率决定过程。近年来，在Ni-Mn-Ga系中发展了一种可在磁场作用下工作的铁磁形状记忆合金。本论文研究了新型的具有B2 bcc有序结构的Co-Ni-Al合金。（1）相变温度：用DSC和VSM测量了马氏体相变温度Ms和居里温度Tc。一些合金在室温以上的相对高温区域中具有Ms和To。这一结果表明Co-Ni-Al合金是一种很有前途的FSMA的候选材料。(2)晶体结构：母相和马氏体相分别具有B_2和L_1_0结构。L1_0相的c/a比为0.81。(3)形状记忆和力学性能：与γ相共存改善了合金的延展性，并且可以通过训练处理获得完美的形状记忆。(4)磁性：使用单晶测定奥氏体和马氏体相的磁各向异性，并检测到约0.3%的磁致伸缩。(5)FSM线材，具有0.5至1.0mmf的FSM线材可以通过常规的轧制和拉拔技术生产。所获得的线显示出伪弹性行为。

项目成果

Y.Murakami: "Magnetic domain structures in Co-Ni-Al ferromagnetic shape-memory alloys studied by Lorents microscopy and electron holography"Acta Materialia. 50. 2173-2184 (2002)

Y.Murakami：“通过洛伦兹显微镜和电子全息术研究 Co-Ni-Al 铁磁形状记忆合金的磁畴结构”Acta Materialia。

K.Oikawa, F.Gejima, T.Ohmori, R.Kainuma, K.Ishida: "Phase equilibria and phase transformations in new B2-type ferromagnetic shape memory alloys of Co-Ni-Ga and Co-Ni-Al systems"Materials Transactions. 42. 2472-2475 (2001)

K.Oikawa、F.Gejima、T.Ohmori、R.Kainuma、K.Ishida：“Co-Ni-Ga 和 Co-Ni-Al 系新型 B2 型铁磁形状记忆合金中的相平衡和相变”材料

Y.Murakami, D.Shindo, K.Oikawa, R.Kainuma, K.Ishida: "Magnetic domain structures in Co-Ni-Al ferromagnetic shape-memory alloys studied by Lorents microscopy and electron holography"Acta Materialia. 50. 2173-2184 (2002)

Y.Murakami、D.Shindo、K.Oikawa、R.Kainuma、K.Ishida：“通过洛伦兹显微镜和电子全息术研究 Co-Ni-Al 铁磁形状记忆合金中的磁畴结构”Acta Materialia。

H.Morito: "Magnetocrystalline anisotropy in single-crystal Co-Ni-Al ferromagnetic shape-memory alloy"Applied Physics Letters. 81・9. 1657-1660 (2002)

H.Morito：“单晶 Co-Ni-Al 铁磁形状记忆合金中的磁晶各向异性”应用物理快报 81・9（2002）。

K.Oikawa: "Promising ferromagnetic Ni-Co-Al shape memory alloy system"Applied Physics Letters. 79・20. 3290-3292 (2001)

K.Oikawa：“有前景的铁磁 Ni-Co-Al 形状记忆合金系统”《应用物理快报》79・20 (2001)。