Research and Development of Pervaporation Membrane Reactor

渗透蒸发膜反应器的研究与开发

• 批准号: 15360414
• 负责人: KITA Hidetoshi
• 金额: $ 8.45万
• 依托单位: Yamaguchi University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2003
• 资助国家: 日本
• 起止时间: 2003 至 2004
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-15360414/
• 关键词: Membrane Reactor; Zeolite Membrane; Molecular Sieve Carbon Membrane; Pervaporation; Micrporous Materials; Membrane Separation

We described the fabrication of a pervaporation membrane reactor for the esterification reaction in order to shift the equilibrium in favor of the ester formation and to improve the conversion of the reaction and a novel pervaporation catalytic membrane reactor for the epoxidation of ally chloride by TS-1 membranes. We have reported the performance of zeolitic membranes and carbon membranes which are the most favorable one for pervaporation. Here, we reported on the hydrothermal synthesis of zeolite MOR, BEA and TS-1 membranes and their pervaporation properties. Synthetic parameters such as the reaction time, temperature, molar ratio of the starting gel, aging, and seed coating were investigated in order to optimize the pervaporation performance of the membrane. Molecular sieve carbon membranes derived from phenolic resin and lignin derivatives were also reported.

为了改变酯化反应的平衡，提高反应的转化率，我们研制了一种用于酯化反应的渗透汽化膜反应器，并以TS-1膜为催化剂制备了一种新型的渗透汽化催化膜反应器，用于氯丙烯的环氧化反应。本文报道了渗透汽化膜中最理想的分子筛膜和炭膜的性能。本文报道了水热法合成莫尔、沸石和TS-1分子筛膜及其渗透汽化性能。考察了反应时间、温度、起始凝胶摩尔比、老化、种子包衣等工艺参数对膜渗透汽化性能的影响。还报道了以酚醛树脂和木质素衍生物为原料制备的分子筛炭膜。

项目成果

メンブレンリアクター

膜反应器

• 发表时间: 2004

Hidetoshi Kita: "Fabrication and Application of Zeolite Membranes"Mat.Res.Soc.Symp.Proc.. 752. 239-249 (2003)

Hidetoshi Kita：“沸石膜的制造和应用”Mat.Res.Soc.Symp.Proc.. 752. 239-249 (2003)

Fabrication of TS-1 Catalytic Membrane Reactor for the Selective Oxidation Reaction

选择性氧化反应TS-1催化膜反应器的研制

• 发表时间: 2005
• 期刊: Trans.Mat.Res.Soc.Jpn 30(in press)
• 作者: X.Zhang;X.Chen Hklto;K.Okamoto
• 通讯作者: K.Okamoto

Synthesis of Zeolite Beta Membrane and its Pervaporation Properties

β沸石膜的合成及其渗透汽化性能

• 发表时间: 2004
• 期刊: Trans.Mat.Res.Soc.Jpn. 29
• 作者: X.Li;H.Kita;K.Okamoto
• 通讯作者: K.Okamoto

特許 メンブレンリアクター

专利膜反应器

• 发表时间: 2004