Creation of Metal-mediated Nanolink Supramolecules

本研究旨在创造金属介导的纳米连接超分子，在固体表面显示特定的化学和物理性质和动态功能。在此基础上，建立了人工金属- dna连接碳纳米管电极的电导测量方法、马格努斯型金属堆在分子笼中的排列方法、肟型大环合成金属丝的方法。这些发现表明，这种超分子金属配合物作为纳米连接分子的关键材料是有用的。

This study aimed at creation of metal-mediated nanolink supramolecules that shows specific chemical and physical properties and dynamic functions on the surface of a solid. As the As the result, a method of conduction measurement in artificial metallo-DNA linking carbon nanotube electrodes, an arrangement of Magnus'-type metal stacks in a molecular cage, a synthetic method of metal wire using an oxime-type macrocycle have been established. These findings show that such supramolecular metal complexes are useful for nanolink molecules as key materials.