Heterometallic complexes with lanthanide and coinage metal centres for CO2 reduction

用于二氧化碳还原的具有镧系元素和造币金属中心的异金属配合物

• 批准号: 512475913
• 负责人: Dr. Rouven Pfleger
• 金额: --
• 依托单位: Kemisk Institut
• 依托单位国家: 德国
• 项目类别: WBP Fellowship
• 财政年份: 2022
• 资助国家: 德国
• 起止时间: 2021-12-31 至 2023-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/512475913?language=en
• 关键词: Heterometallic; complexes; lanthanide; coinage; metal

Anthropogenic climate change is one of the largest contemporary problems. The probability for natural disasters grows with increasing pace. To find solutions, researchers from different fields have to work together. Furthermore, a carbon neutral society needs solutions for the supply of basic chemicals not depending on fossil resources. We propose a project that tackles both the removal of carbon dioxide from atmosphere and the production of small organic molecules with electrochemical measures and interdisciplinary collaboration for optimisation. This utilises a new approach by investigating collaborative effects of electrocatalytic reduction of CO2 by lanthanide-coinage metal coordination compounds. Existing heterometallic complexes will be screened for these properties and with the knowledge gained new compounds will be synthesised. Together with material scientists and theoreticians we want to elaborate a better understanding of the underlying processes and ideally show the applicability towards the end of the project.

人为气候变化是当代最大的问题之一。发生自然灾害的可能性正在以越来越快的速度增长。为了找到解决方案，来自不同领域的研究人员必须共同努力。此外，碳中和社会需要不依赖化石资源的基本化学品供应解决方案。我们提出了一个项目，解决了从大气中去除二氧化碳和生产小有机分子的电化学措施和跨学科合作的优化。这利用了一种新的方法，通过研究协同效应的电催化还原CO2的镧系元素钴金属配位化合物。现有的异金属配合物将筛选这些性能，并与获得的知识将合成新的化合物。与材料科学家和理论家一起，我们希望更好地理解潜在的过程，并在项目结束时展示其适用性。