Multi-Dimensional Interactions in Ensembled Molecular System
Multi-Dimensional Interactions in Ensembled Molecular System
批准号:
09045035
负责人:
OKU Akira
金额:
$2.5万
依托单位国家:
日本
项目类别:
Grant-in-Aid for international Scientific Research
财政年份:
1997
资助国家:
日本
项目状态:
已结题
起止时间:
1997 至 1998
中文摘要
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英文摘要
The elucidation of multi-dimensional interactions in ensembled molecular system is of significant importance for the molecular-level understanding of biological processes, for the functional design of advanced materials, and for the molecular design of pharmaceuticals and agrochemicals, In the present research project, we corroborated with the research group of Prof. Ackerman of Washington university (USA) to promote die extensive utilization of three-dimensional structural-analysis system recently introduced to our institute.Two seminars were held for the researchers of our institute on the theoretical and practical aspects of a high-field nuclear magnetic resonance (MR) spectrometry as well as high-resolution mass spectrometry. Six professors of our institute visited Washington university to corroborate on the following specific research projects : (1) development of a rationally designed asymmetric catalysts based on the multi-dimensional interactions of chiral molecules, (2) quantitative treatment of the relation between the solid-phase function of organic materials and their NMR spectra, and (3) molecular design of bioactive molecules based on die molecular-level understanding of the multi-dimensional interactions.
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T.Kamada: "Diastereoselective α-Alkoxylation of Lactamide N-Alkyl Groups via Intramolecular Formation of Oxonium Ions as the Key Intermediate" J.Chem.Soc.Perkin 1. 3381-3388 (1998)
T.Kamada:“通过分子内形成氧鎓离子作为关键中间体对乳酰胺 N-烷基进行非对映选择性 α-烷氧基化”J.Chem.Soc.Perkin 1. 3381-3388 (1998)
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A.Oku et al.: "Three-and Four-Carbon Elongating Ring-Expansion Reaction of Cyclic Acetals to Medium-Sized Dioxacycloalkenones.Utilization of Intramolecular Formation of Oxonium Ylides." J.Org.Chem.62. 2123-2129 (1997)
A.Oku 等人:“环状缩醛到中等尺寸二氧杂环烯酮的三碳和四碳扩环反应。氧鎓叶立德分子内形成的利用”。
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鎌田 徹: "Diastereoselective a-Alkoxylation of Lactamide N-Alkyl Groups via Intramolecular Formation of Oxonium Ions as the Key Intermediate" J.Chem.Soc.Perkin 1. 3381-3388 (1998)
Toru Kamata:“通过分子内形成氧鎓离子作为关键中间体对乳酰胺 N-烷基进行非对映选择性 α-烷氧基化” J.Chem.Soc.Perkin 1. 3381-3388 (1998)
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T.Harada et al.: "A Novel 1,2-Migration of Arylzincates Bearing a Leaving Group at Benzylic Position : Application to a Three-Component Coupling of p-Iodobenzyl Derivatives." Tetrahedron. 54. 9317-9332 (1998)
T.Harada 等人:“在苯甲基位置带有离去基团的芳基锌酸盐的新型 1,2-迁移:在对碘苄基衍生物三组分偶联中的应用”。
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A.Oku: "Donor-Acceptor Photocatalysis System Illustrated by the Intramolecular Cyclization of a Cyclopropanone Acetal Tethered to Cyclohexen-2-one." Bull.Chem.Soc.Japan,. 72(in press). (1999)
A.Oku:“通过与环己烯-2-酮相连的环丙酮缩醛的分子内环化来说明供体-受体光催化系统。”
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共 19 条
Study on the Monomer Recycling of Plastic Wastes to Feedstock Chemicals.
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批准号:17560727
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$2.11万
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财政年份:2005
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负责人:OKU Akira
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依托单位:
Reaction Design of Medium-sized Ring Structure Based on the Working Hypothesis of Ethereal Oxonium Ylide Formation
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批准号:08455416
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$4.93万
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财政年份:1996
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负责人:OKU Akira
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依托单位:
Novel Carbon-Carbon Bond Formation Utilizing Selective C-H Bond Insertion by Carbenes.
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批准号:63470080
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项目类别:Grant-in-Aid for General Scientific Research (B)
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资助金额:$3.26万
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财政年份:1988
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负责人:OKU Akira
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依托单位:
海外基金