Development of marine notes in algae.
Development of marine notes in algae.
批准号:
09556047
负责人:
KAJIWARA Tadahiko
金额:
$3.07万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (B)
财政年份:
1997
资助国家:
日本
项目状态:
已结题
起止时间:
1997 至 1999
中文摘要
有了用于藻类中新鲜海洋注释开发的研究的一部分,后续的研究结果已经获得。一种新的Heme蛋白质,在第一章中催化了多饱和脂肪酸的氧化生成的氧化脂蛋白,新氯苯酚的两种效应和新氯苯酚的减少,都是化学-酶合成物成功地获得的,及其在第二章中发现的吸引力缺陷特性。第三章中发现的characteristic长链醛的生物合成中间体被识别为(2 R)-绿色藻类中的羟基脂肪酸。Z)-unsaturated dienenals and trienals of C-D217 C-D216 C-D2were stereoselectively synthesized and their olfactory evaluation showed a variety of applications in perfume industry in Chapter IV。
英文摘要
With a part of research for development of fresh marine notes in algae, following research results were obtained. A novel heme protein, which catalyzes oxygenation of polyunsaturated fatty acids affording oxylipins in Chapter I.Both enantiomers of neodictyoprolene and neodictyoprolenol reminiscent of algae, were successfully obtained by chemo-enzymatic syntheses, and their attractive olfactory properties were found in Chapter II.The biosynthetic intermediates of characteristic long-chain aldehydes were identified as (2R)-hydrperoxy fatty acids in green algae in Chapter III.The (Z)-unsaturated dienenals and trienals of CィイD217ィエD2 and CィイD216ィエD2 were stereoselectively synthesized and their olfactory evaluation showed a variety of applications in perfume industry in Chapter IV.
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梶原 忠彦: "海藻バイオフレーバー"化学工業. 49・9. 703-708 (1998)
梶原忠彦:“海藻生物香料”化学工业49・9(1998)。
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AKAKABE, Yoshihiko et al: "Odor contribution of volatile compounds of marine algae on seacoast."Jpn. J. Taste Smell Res.. 6. 469-472 (1999)
AKAKABE、Yoshihiko 等人:“海岸海藻挥发性化合物的气味贡献。”Jpn。
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赤壁善彦,松井健二,梶原忠彦: "海藻揮発成分の海辺の香りへの寄与について"日本味と匂学会誌. 6・3. 469-472 (1999)
赤部义彦、松井贤二、梶原忠彦:“海藻挥发性成分对海边香气的贡献”日本味觉学会杂志 6・3(1999)。
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梶原 忠彦: "沿岸の環境圏(平野敏行監修)「海洋のアメニティーに関する科学」"(株)フジ・テクノシステム、東京. 1389-1393 (1998)
Tadahiko Kajiwara:“沿海环境领域(平野俊之监督)‘海洋设施科学’”Fuji Techno System Co., Ltd.,东京 1389-1393 (1998)。
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AKAKABE, Yoshihiko et al: "Highly enantioselective α-hydroperoxylation in Ulva pertusa."Tetrahedon Lett.. 40. 1137-1140 (1999)
AKAKABE、Yoshihiko 等人:“石莼中的高度对映选择性 α-氢过氧化作用。”Tetrahedon Lett.. 40. 1137-1140 (1999)
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共 26 条
New sex pheromones in marine algae and their biosynthesis.
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批准号:11660112
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$0.7万
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财政年份:1999
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负责人:KAJIWARA Tadahiko
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依托单位:
Dynamic aspect of male gamete-attracting activity in marine algae.
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批准号:07660140
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$1.22万
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财政年份:1995
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负责人:KAJIWARA Tadahiko
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依托单位:
Biogeneration and Secretion of Sex Pheromones in Female Gametes of Marine Algae.
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批准号:03806022
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项目类别:Grant-in-Aid for General Scientific Research (C)
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资助金额:$1.15万
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财政年份:1991
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负责人:KAJIWARA Tadahiko
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依托单位:
Production of Seaweed Flavor by using Marine Biotechnology
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批准号:02556025
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项目类别:Grant-in-Aid for Developmental Scientific Research (B)
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资助金额:$1.66万
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财政年份:1990
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负责人:KAJIWARA Tadahiko
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依托单位:
Formation and Secretion of Sex-Attractants from Motile Gametes of Marine Algae by Settling.
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批准号:01560153
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项目类别:Grant-in-Aid for General Scientific Research (C)
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资助金额:$1.34万
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财政年份:1989
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负责人:KAJIWARA Tadahiko
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依托单位:
海外基金