Joint Research on Quantum Control of Reaction Dynamics

反应动力学量子控制联合研究

• 批准号: 10044054
• 负责人: FUJIMURA Yuichi
• 金额: $ 1.41万
• 依托单位: TOHOKU UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B).
• 财政年份: 1998
• 资助国家: 日本
• 起止时间: 1998 至 1999
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10044054/
• 关键词: vantum control; wave packet; orientation; laser control; photon-polarization; chemical reaction; hydrogen cyanide; electronic wave packet; 化学反応・ダイナミクス; クーロン爆発; 反応ダイナミクス; コヒーレントコントロール; レーザー制御; フェムト秒化学

The main purpose of this research project was to develop a theory for quantum control of chemical reaction dynamics. For this purpose, we have concentrated ourselves to three subjects : 1) control of nuclear wave packets by polarized laser lights, 2) quantum control of molecular orientation and 3) exact solutions of both nuclear and electronic wave packet motion. The results of these subjects are summarized as follows.1. Control of nuclear wave packets by polarized laser pulsesWe have developed a quantum control theory of reactions of multidimensional system by take into account effects of photon-polarization. This theory has been applied to isomerization of hydrogen cyanide induced by two linearly polarized laser pulses and has proved that such polarized laser pulses are effectively promote rates of the isomerization. Such double polarized pulses are also used to control chemically interesting reactions, such as selective preparation of enantiomers from racemic body.2. Quantum control … More of molecular orientationIt is very important to orient molecules in gas phase in order to control gas-phase reactions. We have developed a theory of molecular orientation, which is based on interferences between dipole transitions and non resonant Raman scattering. The variables are frequencies ω and 2ω of two-photon fields, its phase differences and amplitudes of the photon fields. This theory has been applied to HCN by performing abinitio MO calculation of dipole moment and polarizability functions. Effects of rotations are taken into account.3. Exact solutions of both nuclear and electronic wave packet motionIn order to describe ultra short dynamics of molecules under intense pulse laser, which brings about Coulomb explosions, it is essential to treat both electrons and nuclei as wave packets. We have succeeded in exactly solving time-dependent Schroedinger equation of a simple diatomic molecules in terms of wave packets. This is base on a dual transformation to avoid divergence of energy at critical points. Less

该研究项目的主要目的是发展化学反应动力学的量子控制理论。为此，我们集中研究了三个课题：1）用偏振激光控制原子核波包，2）分子取向的量子控制，3）原子核和电子波包运动的精确解。这些课题的研究结果总结如下：1.利用偏振激光脉冲控制原子核的波包我们发展了一个考虑光子偏振效应的多维反应的量子控制理论。将这一理论应用于两束线偏振激光脉冲诱导的氰化氢异构化反应中，证明了线偏振激光脉冲能有效地促进异构化反应的速率。这种双极化脉冲也用于控制化学上感兴趣的反应，例如从外消旋体选择性制备对映体。量子控制 ...更多信息 为了控制气相反应，使分子在气相中取向是非常重要的。我们发展了一种基于偶极跃迁和非共振拉曼散射干涉的分子取向理论。变量为双光子场的频率ω和2ω、相位差和振幅。该理论已被应用到HCN进行从头计算的偶极矩和极化率函数。考虑了旋转的影响.原子核和电子波包运动的精确解为了描述分子在强脉冲激光作用下的超短动力学过程，即库仑爆炸，必须将电子和原子核都看作波包。我们成功地用波包精确求解了简单双原子分子的含时薛定谔方程。这是基于一个双重的转换，以避免发散的能量在临界点。少

项目成果

I.Kawata: "Adiabatic and diabatic response of H_2^+ to an intense ten to second laser pulse"J.Chem.phys.. 110・23. 11152-11165 (1999)

I.Kawata：“H_2^+ 对十秒激光脉冲的绝热和非绝热响应”J.Chem.phys.. 110・23（1999）。

H.Kono: "Magnetic field effects on the dynamics of a Rydberg electron: The residence time near the core"J.Chem.phys.. 110・24. 10895-10902 (1999)

H.Kono：“磁场对里德伯电子动力学的影响：核心附近的停留时间”J.Chem.phys.. 110・24（1999）。

K. Hoki: "Quantum control of NaI predissociation in subpicosecond and several-picosecond time regimes"J. Phys. Chem.. 103(32). 6301 (1999)

K. Hoki：“亚皮秒和几皮秒时间范围内 NaI 预解离的量子控制”J。

Y.Watanabe: "Photon polarization effects en quantum control of isomerization of hydrogen cyanide"J.Mol.Struct.(THEO CHEM). 461-462. 317-324 (1999)

Y.Watanabe：“氰化氢异构化的量子控制中的光子偏振效应”J.Mol.Struct.(THEO CHEM)。

Y. Ohtsuki: "Quantum Control of Nuclear Wave Packets by Locally Designed Optical Pulses"J. Chem. Phys.. 109(21). 9318 (1998)

Y. Ohtsuki：“通过局部设计的光脉冲对核波包进行量子控制”J。