Novel barrier products: synthesis design using controlled radical polymerization in dispersed systems

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Personal barrier products (eg surgical and industrial rubber gloves) are currently manufactured using emulsion polymerization synthesis methods that have evolved little in 50 years. A dramatic new method for controlling polymer architecture, developed by a team led by the CI and Dulux for paints, also has the potential to tailor-make barrier products, from less hazardous raw materials. This project commences the fundamental research for understanding the mechanisms involved in using this method with butadiene, and the mechanical properties of the resulting novel block copolymers. This science would later be applied by the industrial partner to significantly improve their barrier products.