Design and Development of the Transition Metal Complexes Having Multi Functional Properties.
具有多功能特性的过渡金属配合物的设计和开发。
基本信息
- 批准号:07304046
- 负责人:
- 金额:$ 1.66万
- 依托单位:
- 依托单位国家:日本
- 项目类别:Grant-in-Aid for Scientific Research (B)
- 财政年份:1995
- 资助国家:日本
- 起止时间:1995 至 1996
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
Transition metal complexes which are located between organic and inorganic materials hava a possibility of various kinds of multi-functional properties mixed with optical, magnetic or transport properties. In order to search and develop new multifunctional properties for transition metal complexes, we have organized the research project, grant-in-aid for scientific research whose title is "Design and Development of the Transition Metal Complexes Having Multi-Functional Properties".During the term of the project (1995-1996), the noticeable results of our project are following ; (1) Field induced insulator-to-metal transition in (BETS) _2FeCl_4, which is driven by the d-pi interaction, (2) Competition between the superconducting and antiferromagnetic phases in (BETS) _2Ga_<1-X>Fe_XCl_4, (3) An exotic metal-insulator transition driven by the d-pi electron transfer coupled with proton transfer in [Pd (H_2DAG) (HDAG)]TCNQ (M=Ni, Pd, Pt), (4) Development of new ferromagnets and ferrimagnets, (5) Development of new spin crossover complexes, (6) Existence of dense nonlinear excitations such as solitons or polarons for mixed-valence MX chain system, (7) Metal-insulator transition in mixed-valence MMX-chain system, (8) Development of highly nonlinear optics (SHG) for transition metal cluster complexes, (9) Photo-induced ligand-driven crystalline vibration for coordination polymer.
过渡金属配合物位于有机和无机材料之间,具有多种多功能性质,并具有光学、磁性或输运性质。为了探索和开发过渡金属配合物的新的多功能性质,我们组织了科研资助项目“具有多功能性质的过渡金属配合物的设计与开发”,在项目期间,(1995-1996年),我们的项目取得了以下显著成果:(1)(BETS)_2FeCl_4的场致绝缘体-金属相变,它是由d-pi相互作用驱动的,(2)(BETS)_2Ga_Fe_XCl_4中超导相与反铁磁相的竞争<1-X>;(3)[Pd(H_2DAG)(HDAG)]TCNQ中d-pi电子转移与质子转移耦合驱动的奇异金属-绝缘体转变(M=Ni,Pd,Pt),(4)新的铁磁体和亚铁磁体的开发,(5)新的自旋交叉配合物的开发,(6)混合价MX链系统中密集非线性激发如孤子或极化子的存在,(7)混合价MMX链系统中的金属-绝缘体转变,(8)过渡金属簇合物的高非线性光学(SHG)的开发,(9)配位聚合物的光诱导配体驱动的晶体振动。
项目成果
期刊论文数量(199)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
G. Matsubayashi et al.: "Isolation and Spectroscopic Properties of [Re_2 (C_3S_5) _5] ^<2-> Anion Complexes and Electrical Conductivities of the Oxidized Species…" J. Chem. Soc. Dalton Trans.(in press.). (1995)
G. Matsubayashi 等人:“[Re_2 (C_3S_5) _5] ^<2-> 阴离子配合物的分离和光谱特性以及氧化物质的电导率……”J. Chem Soc。 (1995)
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Y. Maeda et al.: "Mixed-Valence Dinuclear Iron Complexes with a Nonadentate Polypyridine Ligand: High-Spin Iron (II) -Low-Spin Iron (III)." J. Chem. Soc. Dalton Trans.3533-3536 (1995)
Y. Maeda 等人:“具有九齿聚吡啶配体的混合价双核铁络合物:高自旋铁 (II) -低自旋铁 (III)”。
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N.Ishikawa and Y.Kaizu: "Electronic Structure of One-Electron Oxidation Product of Triple-Decker Lutetium Phthalocyanine Trimer" Chem.Phys.Lett.236. 50-56 (1995)
N.Ishikawa 和 Y.Kaizu:“三层镥酞菁三聚体的单电子氧化产物的电子结构”Chem.Phys.Lett.236。
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H.Kobayashi,H.Tomita,T.Udagawa,T.Naito and A.Kobayashi: "New Organic Superconductor,λ-(BETS)_2GaCl_4 and Metal-Insulator Transition of BETS Conductor with Magnetic Anions (BETS=bis(ethylenedithio)tetraselenafulvalene)" Synth.Metals. 70. 867-870 (1995)
H.Kobayashi、H.Tomita、T.Udakawa、T.Naito 和 A.Kobayashi:“新型有机超导体、λ-(BETS)_2GaCl_4 和带有磁性负离子的 BETS 导体的金属-绝缘体转变(BETS=双(乙撑二硫)四硒富瓦烯)”合成金属。70。867-870(1995)
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H.Ito,M.Kubota,Y.V.Sushko,N.Kojima,G.Saito and T.Ishiguro: "Temperature-Pressure Phase Diagrams of Hydrogenated and Deuterated κ-(BEDT-TTF)_2Cu [N(CN)_2] Cl" Synth.Metals. 70. 925-926 (1995)
H.Ito、M.Kubota、Y.V.Sushko、N.Kojima、G.Saito 和 T.Ishiguro:“氢化和氘化 κ-(BEDT-TTF)_2Cu [N(CN)_2] Cl 的温压相图”合成金属。70. 925-926 (1995)
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KOJIMA Norimichi其他文献
KOJIMA Norimichi的其他文献
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{{ truncateString('KOJIMA Norimichi', 18)}}的其他基金
Development of New Molecular Magnetism Based on Dynamical Spin Equilibrium
基于动态自旋平衡的新型分子磁学研究进展
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26620057 - 财政年份:2014
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Development of pH-Sensitive Spin-Crossover Complex Film and Direct Observation of Proton Flow
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24655115 - 财政年份:2012
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Grant-in-Aid for Challenging Exploratory Research
Progress of Organic-Inorganic Hybrid Complexes Having NovelSuccessive Physical Properties Coupled with Photon-Spin-Charge
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22350057 - 财政年份:2010
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Dynamical Spin Crossover Phenomenon in Organic-Inorganic Composite Complex and Its Development to Molecular System
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18350069 - 财政年份:2006
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Grant-in-Aid for Scientific Research (B)
Progress of Conjugated Phenomena Coupled with Spin and Photon for Assembled Hetero-Molecular System by Using Coordination Space
利用配位空间组装异质分子体系自旋与光子耦合共轭现象研究进展
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16074205 - 财政年份:2004
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$ 1.66万 - 项目类别:
Grant-in-Aid for Scientific Research on Priority Areas
Study on the dynamical spin-crossover phenomenon coupled with spinm and charge, and its multifunctionalities
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15350078 - 财政年份:2003
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Research on Multifunctional Properties Coupled with Photon and Spin for Transition-Metal Complexes
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10440203 - 财政年份:1998
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$ 1.66万 - 项目类别:
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05452040 - 财政年份:1993
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$ 1.66万 - 项目类别:
Grant-in-Aid for General Scientific Research (B)
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