Synthetic Use of Poly[styrene(iodoso diacetate)]for Organic Reactions

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Preparation and synthetic use of poly[styrene(iodoso diacetate)] have been established. Thus, poly[styrene(iodoso diacetate)] is sufficiently reactive for the iodination of aromatics, oxidative 1,2-aryl migration of alkyl aryl ketones, alpha-hydroxylation of ketones, and oxidations of hydroquinones and sulfides as (diacetoxyiodo)benzene does. Here, the reactions with poly[styrene(iodoso diacetate)] is very useful for these organic reactions, because of the simple operation, thus the filtration gives the products and poly(iodostyrene), and poly[styrene(iodoso diacetate)] can be regenerated by the oxidation of recovered poly(iodostyrene) and reused.