Development of well-orderd organizations using self-organized electroactive polymers

使用自组织电活性聚合物开发有序组织

• 批准号: 12650888
• 负责人: RIKUKAWA Masahiro
• 金额: $ 1.66万
• 依托单位: Sophia University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2000
• 资助国家: 日本
• 起止时间: 2000 至 2001
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12650888/
• 关键词: Well-organized structure; Polythiophene; Electrostatic interaction; Self-assembly films; Conducting polymer; 1-D wire; Band gap; Third-order optical non-linearity; 自己組織性; 立体規則性; Langmuir-Blodgett法; 光学特性; 電気特性; 組織化

1) Synthesis of self-organized polymers by novel polymerization methodNovel regiocontrolled polythiophene derivatives could be synthesized in this research project. In addition, polyaniline microspheres in sub-micrometer order diameter were prepared by the polymerization method developed by our group.2) Study on self-organization behavior and structuresThe relationship between self-organization and regioregularity for regiocontrolled polymers was investigated by using X-ray diffraction measurements. The regioregularity for regiocontrolled polymers induces the self-organization.3) Preparation of ultra thin films and self-organizationUltra thin films of regiocontrolled polymers were fabricated by Langmuir-Blodgett method. These dipping processes improved the self-organization of ultra thin films. Self-assembly films of these polymers were also prepared by the electrostatic interaction between polycations and polyanions.4) Investigation of electrical and optical properties for self-organized materialsThe self-organization and well-defined structures result in higher electrical conductivity and low band gaps for self-organized materials.

1) Synthesis of self-organized polymers by novel polymerization methodNovel regiocontrolled polythiophene derivatives could be synthesized in this research project. In addition, polyaniline microspheres in sub-micrometer order diameter were prepared by the polymerization method developed by our group.2) Study on self-organization behavior and structuresThe relationship between self-organization and regioregularity for regiocontrolled polymers was investigated by using X-ray diffraction measurements. The regioregularity for regiocontrolled polymers induces the self-organization.3) Preparation of ultra thin films and self-organizationUltra thin films of regiocontrolled polymers were fabricated by Langmuir-Blodgett method.这些浸渍工艺改善了超薄膜的自组织性。 Self-assembly films of these polymers were also prepared by the electrostatic interaction between polycations and polyanions.4) Investigation of electrical and optical properties for self-organized materialsThe self-organization and well-defined structures result in higher electrical conductivity and low band gaps for self-organized materials.

项目成果

Y. Tabuehi: "Incorporation of conjugated polydiacetylene systems into organic-inorganic quantum-well structures"Chem. Commun. 2592-2593 (2001)

Y. Tabuehi：“将共轭聚二乙炔系统纳入有机-无机量子阱结构”Chem。

M. Kaneto: "Photovoltaic cell using high mobility poly(alkylthiophene)s and TiO_2"Synthetic Metals. 121. 1537-1538 (2001)

M. Kaneto：“使用高迁移率聚（烷基噻吩）和 TiO_2 的光伏电池”合成金属。

Y.Tabuchi: "Incorporation of conjugated polydiacetylene systems into organic-inorganic quantum-well structures"Chem.Commun. 2592-2593 (2001)

Y.Tabuchi：“将共轭聚二乙炔系统纳入有机-无机量子阱结构”Chem.Commun。

T.Kobayashi: "Photoluminescence from the even-parity state in polythiophene derivative"J. Phys. Soc. Jpn.. 70. 2517-2520 (2001)

T.Kobayashi：“聚噻吩衍生物偶宇称态的光致发光”J。

K.Kaneto: "Alkyl chain length dependence of Field-Effect mobilities in regioregular poly(3-alkyltniophene)"Jpn.J.Appl.Phys.. 39. L872-L874 (2000)

K.Kaneto：“区域规则性聚（3-烷基噻吩）中场效应迁移率的烷基链长度依赖性”Jpn.J.Appl.Phys.. 39.L872-L874（2000）