Development of well-orderd organizations using self-organized electroactive polymers

1)新型聚合方法合成自组装聚合物本研究可以合成新型区域可控的聚噻吩衍生物。此外，还采用本课题组开发的聚合方法制备了亚微米级的聚苯胺微球。2）自组织行为与结构的研究采用X射线衍射方法研究了区域控制聚合物的自组织与区域规整性之间的关系。区域可控聚合物的区域规整性导致了自组织的产生。3）超薄膜的制备与自组织利用Langmuir-Blodgett方法制备了区域可控聚合物超薄膜。这些浸渍工艺改善了超薄膜的自组织性。通过聚阳离子和聚阴离子之间的静电相互作用，制备了这些聚合物的自组装膜。4）自组装材料的电学和光学性质的研究自组装材料的自组织和明确的结构导致其具有较高的电导率和较低的带隙。

1) Synthesis of self-organized polymers by novel polymerization methodNovel regiocontrolled polythiophene derivatives could be synthesized in this research project. In addition, polyaniline microspheres in sub-micrometer order diameter were prepared by the polymerization method developed by our group.2) Study on self-organization behavior and structuresThe relationship between self-organization and regioregularity for regiocontrolled polymers was investigated by using X-ray diffraction measurements. The regioregularity for regiocontrolled polymers induces the self-organization.3) Preparation of ultra thin films and self-organizationUltra thin films of regiocontrolled polymers were fabricated by Langmuir-Blodgett method. These dipping processes improved the self-organization of ultra thin films. Self-assembly films of these polymers were also prepared by the electrostatic interaction between polycations and polyanions.4) Investigation of electrical and optical properties for self-organized materialsThe self-organization and well-defined structures result in higher electrical conductivity and low band gaps for self-organized materials.