Realising highly selective catalysts for continuous chlorine production

实现连续氯生产的高选择性催化剂

• 批准号: DE220100676
• 负责人: Dr Shenlong Zhao
• 金额: $ 30.95万
• 依托单位: The University of Sydney
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Early Career Researcher Award
• 财政年份: 2022
• 资助国家: 澳大利亚
• 起止时间: 2022-01-01 至 2024-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DE220100676
• 关键词: Realising; highly; selective; catalysts; continuous

The aim is to directly electrocatalytic low concentration NaCl solution under mild conditions, to form chlorine gas for the polymers and pharmaceuticals production, enabled by the low dimensional metal-organic framework based catalysts. The project will also gain an atomic-level understanding of the mechanism of CER, based on in-situ spectroscopies e.g., X-ray absorption and Raman. Unlike electrocatalytic chlorine evolution using membrane cell with one membrane only, the project will design a novel integrated reactor system to alleviate the naturally sluggish chlorine evolution reaction, CER, significantly improving the yield and selectivity.

目的是在温和条件下直接电催化低浓度NaCl溶液，形成用于聚合物和药品生产的氯气，使低维金属有机骨架催化剂成为可能。该项目还将基于原位光谱，如x射线吸收和拉曼光谱，获得对CER机制的原子级理解。与单膜电催化析氯不同，该项目将设计一种新型集成反应器系统，以缓解自然缓慢的析氯反应CER，显著提高产率和选择性。