Synthesis of new ionic liquids and construction offunctionalized reaction systems

本研究的目标是以离子液体为介质开发多个反应场，并通过设计复合离子来制备多种功能液体。在本研究中，我发现离子液体在通过Baylis-Hillman型Michael加成反应合成含氟化合物以及在合成2-取代的3-三（或二）氟甲基-2-丙烯醛中具有高的几何异构体选择性的合成效用。此外，我还报道了可重复使用的离子液体-脯氨酸（或醛缩酶抗体38 C2）反应系统的实用性，进行羟醛缩合反应。

The aim of this research area was to develop a few reaction fields by using ionic liquids as media, and to create many functional liquids by designing the composite ions. In this research, I have found that the synthetic utilities of ionic liquids for the synthesis of fluorinated materials via Michael addition with the Bayllis-Hillman type reaction, and for the synthesis of 2-substituted 3-tri-(or di-)fluoromethyl-2-propenals with the high level selectivity of geometric isomers. Further, I have reported the utility of reusable ionic liquid-proline (or aldolase antibody 38C2) reaction system, proceeding the aldol reactions.