High Oxidation State and Related Chemistry of Organic Compounds of Palladium

钯有机化合物的高氧化态及相关化学

• 批准号: DP0342842
• 负责人: Prof Allan Canty
• 金额: $ 30.96万
• 依托单位: University of Tasmania
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2003
• 资助国家: 澳大利亚
• 起止时间: 2003-09-04 至 2008-06-30
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0342842
• 关键词: Oxidation; State; Related; Chemistry; Organic

Palladium is able to form compounds containing palladium-carbon bonds, and compounds of this type occur in applications such as synthesis of organic compounds. The fundamental chemistry of this class of palladium compound is to be explored, in particular for the oxidation state +IV for palladium and with a focus on reactions that are relevant to processes occurring in organic synthesis applications. Particular emphasis is placed on chemistry involving phosphorus compounds and unsaturated organic groups bonded to palladium, and on compounds containing groups that are able to join together to depart from palladium as organic compounds containing carbon-oxygen bonds.

钯能够形成含有钯-碳键的化合物，这种类型的化合物存在于有机化合物的合成等应用中。这类钯化合物的基础化学有待探索，特别是钯的氧化态+IV，重点是与有机合成应用中发生的过程相关的反应。特别强调涉及与钯相连的磷化合物和不饱和有机基团的化学，以及含有能够结合在一起的基团与钯分离的化合物作为含有碳氧键的有机化合物。