Coordination networks based on carbonate and related ions

基于碳酸盐和相关离子的配位网络

• 批准号: DP0343996
• 负责人: Prof Richard Robson
• 金额: $ 26.51万
• 依托单位: The University of Melbourne
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2003
• 资助国家: 澳大利亚
• 起止时间: 2003-01-01 至 2006-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0343996
• 关键词: Coordination; networks; based; carbonate; related

The very familiar carbonate ion will be put to use to generate a very unfamiliar family of new coordination polymers with geometries and topologies of fundamental structural significance. Carbonate's ability to bring associated metal centres into close communication may lead to unusual and possibly useful electrical, magnetic and catalytic properties. The ability to deliberately engineer specifically targeted coordination polymers with predetermined properties or functions would make possible diverse applications of great practical value; the project will contribute significantly to the basis for such capabilities leading to ?designer materials? of the future.

非常熟悉的碳酸根离子将被用来产生一个非常陌生的家庭的新的配位聚合物的几何形状和拓扑结构的基本结构意义。 碳酸盐使相关金属中心紧密联系的能力可能导致不寻常的和可能有用的电，磁和催化性能。 有意识地设计具有预定性质或功能的特定目标配位聚合物的能力将使具有巨大实用价值的多样化应用成为可能;该项目将为这种能力的基础做出重大贡献，从而导致？设计师材料？后事之