Selective Synthesis of Luminescent Metal Complexes by Microwave Thermo-Catalytic Method and Development of Environment Friendly Reaction Processes.

研究了微波热催化选择性合成发光金属配合物的方法。利用各种微波反应设备在微波照射下合成了Ir(III)-多吡啶配合物、Tb（III）和Eu (III)- β-二酮和多吡啶配合物。该方法快速、高收率地制备了各种发光颜色的高强度发光配合物。研究了这些发光配合物的光化学性质。半导体HPA精密微波化学反应器是一种新型的环境友好型反应反应器。利用该设备，可以高效地进行金属配合物和纳米金颗粒的微波合成。作为相关研究，已经合成了液晶金属配合物和有机化合物，并对其理化性质进行了研究。还研究了新型配体的发光金属配合物。

Selective synthesis of luminescent metal complexes by microwave thermo-catalytic method is studied.Luminescent Ir(III)-polypyridine complexes, Tb(III) and Eu (III) complexes with β-diketone and polypyridine ligand have been synthesized under microwave irradiation with various microwave reaction equipments. High Intense luminescent complexes with various emission colors were obtained rapidly with high yields. The photochemical properties of these luminescent complexes were investigated. Semiconductor HPA precise microwave chemical reactor has been newly developed for environment friendly reaction processes. With this equipment, microwave synthesis of metal complexes and nano gold particles has been efficiently carried out.As related study, liquid crystal metal complexes and organic compounds have been synthesized and their physicochemical properties have been studied. Luminescent metal complexes with novel ligands were also studied.