Selective Synthesis of Luminescent Metal Complexes by Microwave Thermo-Catalytic Method and Development of Environment Friendly Reaction Processes.

微波热催化法选择性合成发光金属配合物及环境友好反应工艺开发。

• 批准号: 16350084
• 负责人: MATSUMURA Takeko
• 金额: $ 7.04万
• 依托单位: Minerva Light Laboratory L.C.C.
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2004
• 资助国家: 日本
• 起止时间: 2004 至 2006
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16350084/
• 关键词: Microwave thermo-catalysis; Luminescent complexes; Polypyridine Complexes; Rear earth metal complexes.; Precise microwave reactor; リン光性錯体; ポリピリジン; β-ジケトン; 液晶性; 精密マイクロ波反応装置; 有機EL; 液晶

Selective synthesis of luminescent metal complexes by microwave thermo-catalytic method is studied.Luminescent Ir(III)-polypyridine complexes, Tb(III) and Eu (III) complexes with β-diketone and polypyridine ligand have been synthesized under microwave irradiation with various microwave reaction equipments. High Intense luminescent complexes with various emission colors were obtained rapidly with high yields. The photochemical properties of these luminescent complexes were investigated. Semiconductor HPA precise microwave chemical reactor has been newly developed for environment friendly reaction processes. With this equipment, microwave synthesis of metal complexes and nano gold particles has been efficiently carried out.As related study, liquid crystal metal complexes and organic compounds have been synthesized and their physicochemical properties have been studied. Luminescent metal complexes with novel ligands were also studied.

研究了微波热催化法选择性合成发光金属配合物的方法，在微波辐射条件下，利用不同的微波反应装置，合成了Ir（III）-聚吡啶配合物、Tb（III）和Eu（III）-β-二酮和聚吡啶配合物。高强度的发光配合物，具有各种发射颜色的快速高产率。研究了这些发光配合物的光化学性质。半导体HPA精密微波化学反应器是针对环境友好型反应过程而开发的一种新型反应器。在此基础上，利用微波合成技术成功地合成了金属配合物和纳米金粒子，并合成了液晶金属配合物和有机化合物，研究了它们的物理化学性质。本文还研究了含新型配体的发光金属配合物。

项目成果

講座マイクロ波化学への招待1、マイクロ波化学の原理-マイクロ波の電界と物質の誘電特性-

微波化学课程邀请1、微波化学原理-微波电场与材料介电特性-

• 发表时间: 2006
• 期刊: 化学と教育 54
• 作者: 松村竹子;藤井 知;福岡隆夫;栗原英紀;矢嶋龍彦;久枝良雄;松村竹子
• 通讯作者: 松村竹子

Microwave synthesis of gold nano particles and their surface enhanced Raman spectra

金纳米粒子的微波合成及其表面增强拉曼光谱

• 发表时间: 2007
• 期刊: J.Photo.Soc.Japan 70
• 作者: T.Fukuoka;T.Matsumura;Y.Mori
• 通讯作者: Y.Mori

半導体マイクロ波反応装置の開発

半导体微波反应器的研制

• 发表时间: 2006
• 期刊: ケミカルエンジニヤリング 51
• 作者: 松村竹子;藤井 知;福岡隆夫;栗原英紀;矢嶋龍彦
• 通讯作者: 矢嶋龍彦

Formation of Stable Molecular Glasses of Yttrium(III) of Acyl-alaninate Complexes

酰基丙氨酸钇配合物稳定分子玻璃的形成

• 发表时间: 2004
• 期刊: Chem.Lett.
• 作者: M.Iida;R.Masuda;N.Gerile;Y.Bin;K.Kajiwara
• 通讯作者: K.Kajiwara

金ナノ粒子のマイクロ波合成と表面増強ラマン散乱

金纳米颗粒的微波合成和表面增强拉曼散射

• 发表时间: 2007
• 期刊: 0 70
• 作者: 福岡隆夫;松村竹子;森康維
• 通讯作者: 森康維